Triethoxy(3,3,3-trifluoropropyl)silane

Base Information

• Chemical Name: Triethoxy(3,3,3-trifluoropropyl)silane
• CAS No.: 681-97-0
• Molecular Formula: C9H19F3O3Si
• Molecular Weight: 260.329
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID50529579
• Nikkaji Number: J1.654.923A
• Wikidata: Q82400089
• Mol file: 681-97-0.mol

Synonyms:Silane, triethoxy(trifluoropropyl)-;Triethoxy(3,3,3-trifluoropropyl)silane;86876-45-1;681-97-0;(3,3,3-trifluoropropyl)triethoxysilane;Silane, triethoxy(3,3,3-trifluoropropyl)-;trifluoropropyl triethoxysilane;SCHEMBL180362;(trifluoropropyl)triethoxysilane;DTXSID50529579;MFCD18250269;AKOS008901275;AB72661;MS-20287;(3,3,3-TRIFLUOROPROPYL)-TRIETHOXYSILANE

Chemical Property of Triethoxy(3,3,3-trifluoropropyl)silane

Chemical Property:

• Vapor Pressure: 0.682mmHg at 25°C
• Boiling Point: 192.402°C at 760 mmHg
• Flash Point: 70.162°C
• PSA: 27.69000
• Density: 1.048g/cm³
• LogP: 2.98720
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 8
• Exact Mass: 260.10555548
• Heavy Atom Count: 16
• Complexity: 170

Purity/Quality:

99% ^*data from raw suppliers

(3,3,3-Trifluoropropyl)triethoxysilane 90% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCO[Si](CCC(F)(F)F)(OCC)OCC

Technology Process of Triethoxy(3,3,3-trifluoropropyl)silane

There total 2 articles about Triethoxy(3,3,3-trifluoropropyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2H-pentafluoropropene (690-27-7) + Triethoxysilane (998-30-1) → 1,1,1-trifluoropropane (421-07-8) + triethoxy-(3,3,3-trifluoro-propyl)-silane (681-97-0)

Guidance literature:

With Rh{Si(OEt)₃}(PEt₃)₃; In benzene-d6; at 20 ℃; for 1h; under 150.015 Torr; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.202101508

Reference yield:

2H-pentafluoropropene (690-27-7) + Triethoxysilane (998-30-1) → 1,1,1-trifluoropropane (421-07-8) + 1,1-difluoropropene (430-63-7) + 1,1,1-trifluoropropylene (677-21-4) + trans-1,3,3,3-tetrafluoropropene (29118-24-9) + triethoxy-(3,3,3-trifluoro-propyl)-silane (681-97-0) + (Z)-1,3,3,3-tetrafluoropropene (29118-25-0)

Guidance literature:

With Rh{Si(OEt)₃}(PEt₃)₃; In benzene-d6; at 20 ℃; for 1h; under 150.015 Torr; Reagent/catalyst; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.202101508

Reference yield: 91.0%

1-[N,N-bis(2-hydroxyethyl)amino]-2-propanol (6712-98-7) + triethoxy-(3,3,3-trifluoro-propyl)-silane (681-97-0) → 3-Methyl-1-(3,3,3-trifluorpropyl)silatran (63453-66-7)

Guidance literature:

With sodium ethanolate; In ethanol; Heating;

DOI:10.1007/BF00769800

upstream raw materials:

2H-pentafluoropropene

Triethoxysilane

Downstream raw materials:

3-Methyl-1-(3,3,3-trifluorpropyl)silatran

1-(3,3,3-Trifluoropropyl)silatrane

3,7-dimethyl-1-(3,3,3-trifluoro-propyl)-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane