2-Tetrazene, 1,1,4,4-tetraethyl-

Base Information

• Chemical Name: 2-Tetrazene, 1,1,4,4-tetraethyl-
• CAS No.: 13304-29-5
• Molecular Formula: C8H20N4
• Molecular Weight: 172.274
• DSSTox Substance ID: DTXSID501347947
• Nikkaji Number: J46.111C
• Wikidata: Q63392715
• Mol file: 13304-29-5.mol

Synonyms:2-Tetrazene, 1,1,4,4-tetraethyl-;13304-29-5;N-[(E)-diethylaminodiazenyl]-N-ethylethanamine;Tetraethyl-2-tetrazene;1,1,4,4-Tetraethyl-2-tetrazene;(2E)-1,1,4,4-Tetraethyl-2-tetrazene;CHEBI:151046;DTPTYCXQWZYACS-MDZDMXLPSA-N;DTXSID501347947;(2E)-1,1,4,4-Tetraethyl-2-tetrazene #;Q63392715

Chemical Property of 2-Tetrazene, 1,1,4,4-tetraethyl-

Chemical Property:

• Vapor Pressure: 0.253mmHg at 25°C
• Boiling Point: 205.2°Cat760mmHg
• PKA: 9?+-.0.70(Predicted)
• Flash Point: 77.9°C
• PSA: 31.20000
• Density: 0.91g/cm³
• LogP: 1.95220
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 172.16879665
• Heavy Atom Count: 12
• Complexity: 102

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)N=NN(CC)CC
• Isomeric SMILES: CCN(CC)/N=N/N(CC)CC

Technology Process of 2-Tetrazene, 1,1,4,4-tetraethyl-

There total 5 articles about 2-Tetrazene, 1,1,4,4-tetraethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

diethylamine (109-89-7) + (Z)-1-morpholino-2-phthalimido-diazen-1-oxid (78657-44-0,907167-26-4) → 1,1,4,4,-tetraaethyl-2-tetrazen (13304-29-5) + 2-(diethylcarbamoyl)benzoic acid (4166-52-3) + 1,1-diaethyl-(4,4-oxapentamethylen)-2-tetrazen

Guidance literature:

In dichloromethane; for 0.25h;

DOI:10.1002/hlca.19810640326

Reference yield: 30.2%

1-ethyl-2-(propan-2-ylidene)hydrazine (7422-99-3) + 1,1-diethyldiazenium bromide → aldehyde diethylhydrazone (7422-91-5) + tetraethyl-2-tetrazene (13304-29-5) + Aceton-diaethylhydrazon (16713-36-3) + 3,3-dimethyl-1,5,5-triethyl-3,4-dihydroformazan

Guidance literature:

With triethylamine; at -30 - -20 ℃; Further byproducts given. Title compound not separated from byproducts;

Reference yield: 30.2%

1-ethyl-2-(propan-2-ylidene)hydrazine (7422-99-3) + 1,1-diethyldiazenium bromide → tetraethyl-2-tetrazene (13304-29-5) + 3-methyl-1,5,5-triethyl-3,4-dihydroformazan (51576-32-0) + Aceton-diaethylhydrazon (16713-36-3) + 3,3-dimethyl-1,5,5-triethyl-3,4-dihydroformazan

Guidance literature:

With triethylamine; at -30 - -20 ℃; Further byproducts given. Title compound not separated from byproducts;

upstream raw materials:

1-ethyl-2-(propan-2-ylidene)hydrazine

N,N-diethylhydrazine

N-Nitrosodiethylamine

acetic acid

Downstream raw materials:

3-aza-2-pentene

diethylamine

N,N-diethylnmethylamine

N-methylideneethylamine