Iron carbonyl

Base Information

• Chemical Name: Iron carbonyl
• CAS No.: 37220-42-1
• Molecular Formula: C₅FeO₅
• Molecular Weight: 195.899
• Mol file: 37220-42-1.mol

Synonyms:IRON CARBONYL;IRON PENTACARBONYL

Chemical Property of Iron carbonyl

Chemical Property:

• Melting Point: -21℃
• Boiling Point: 103oC
• PSA: 0.00000
• LogP: -1.04250

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Catalyst in organic reactions, carbonyl iron for high-frequency coils. Iron pentacarbonyl is a useful dehalogenating and carbonylating agent.

Technology Process of Iron carbonyl

There total 220 articles about Iron carbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

triiron dodecarbonyl (17685-52-8) → iron pentacarbonyl (13463-40-6,37220-42-1)

Guidance literature:

With carbon monoxide; In n-heptane; Irradiation (UV/VIS); soln. of Fe3(CO)12 in n-heptane is irradiated for 30 min in slow streamof CO;

DOI:10.1016/S0277-5387(00)86658-9

Reference yield: 80.0%

iron (7439-89-6) → iron pentacarbonyl (13463-40-6,37220-42-1)

Guidance literature:

With carbon monoxide; tetrabutylammomium bromide; In methanol; Electrochem. Process; CO 37 bar, electrolysis (Fe-anode, Bu4NBr, 293 K, 30 mA, 1.5 V, 168 h); distn., dried (P2O5);

Reference yield:

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + cis-[Fe(CO)4Cl2] (21475-90-1,15006-65-2,142036-31-5) → iron pentacarbonyl (13463-40-6,37220-42-1) + tetracarbonyl nickel (13463-39-3,71564-36-8)

Guidance literature:

In hexane; under Ar Fe-complex was suspended in hexane at 0°C, Ni-complex was added, stirred at 0°C for 45 min; filtered, evapd., detected by IR;

DOI:10.1016/S0022-328X(00)84689-6

upstream raw materials:

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

cis-[Fe(CO)4Cl₂]

nitrosyl hexafluorophosphate

{((C₆H₅)3P)2N}⁽¹⁺⁾*{HFe₄(CO)12(CO)}^(1-)={((C₆H₅)3P)2N}{HFe₄(CO)12(CO)}

Downstream raw materials:

cyclopentadienyl iron(II) dicarbonyl dimer

ferrous iodide

iron(II) bromide

Fe(CO)4{As(C₆H₅)3}

Refernces

• 1、 Hayton, Trevor W.,Touchton, Alexander J.,Wu, Guang. "Synthesis of Bis(trityl)iron(II) and Formation of the Iron(0)-Stabilized o, o-Isomer of Gomberg's Dimer". supporting information. p. 4045 - 4049. Retrieved 2021/12/13.
• 2、 Pandey, Swechchha,Raj, K. Vipin,Shinde, Dinesh R.,Vanka, Kumar,Kashyap, Varchaswal,Kurungot, Sreekumar,Vinod,Chikkali, Samir H.. "Iron Catalyzed Hydroformylation of Alkenes under Mild Conditions: Evidence of an Fe(II) Catalyzed Process". supporting information. p. 4430 - 4439. Retrieved 2018/04/05.