2-Tetradecylpentanedioic acid dimethyl ester

Base Information

• Chemical Name: 2-Tetradecylpentanedioic acid dimethyl ester
• CAS No.: 29238-07-1
• Molecular Formula: C₂₁H₄₀O₄
• Molecular Weight: 356.546
• Mol file: 29238-07-1.mol

Synonyms:2-Tetradecylglutaric acid dimethyl ester;2-Tetradecylpentanedioic acid dimethyl ester

Chemical Property of 2-Tetradecylpentanedioic acid dimethyl ester

Chemical Property:

• PSA: 52.60000
• LogP: 5.82000

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Tetradecylpentanedioic acid dimethyl ester

There total 6 articles about 2-Tetradecylpentanedioic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + Methyl oleate (112-62-9) → dimethyl 2-hexadecylmalonate (23130-42-9) + dimethyl 1,19-nonadecandioate (23130-41-8) + dimethyl 2-methyloctadecane-1,18-dioate (41240-36-2) + 9-Methoxycarbonyl-octadecansaeure-methylester (6842-84-8) + 8-Methoxycarbonyl-octadecansaeure-methylester (34665-10-6) + 11-Methoxycarbonyl-octadecansaeure-methylester (34643-98-6) + 12-Methoxycarbonyl-octadecansaeure-methylester (25751-93-3) + 10-Methoxycarbonyl-octadecansaeure-methylester (6858-79-3) + 2-Pentadecyl-succinic acid dimethyl ester (41240-29-3) + 2-Undecyl-octanedioic acid dimethyl ester (41240-32-8) + dimethyl 2-ethylheptadecane-1,17-dioate (41240-35-1) + dimethyl 2-propylhexadecane-1,16-dioate (41240-34-0) + 2-Tridecyl-hexanedioic acid dimethyl ester (41240-31-7) + Methyl-4-methoxycarbonyloctadecanoat (29238-07-1) + C20H38O4 + C20H38O4 + C21H40O4

Guidance literature:

With [(o-di(1-adamantyl)phosphino-benzyl-di(adamantyl)phosphine)Pd(OTf₂)]; carbon monoxide; at 90 ℃; for 120h; under 15001.5 Torr; Reagent/catalyst; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201301124

Reference yield:

methyl myristoate (124-10-7) → Methyl-4-methoxycarbonyloctadecanoat (29238-07-1)

Guidance literature:

Multi-step reaction with 4 steps

2: KOH / 2-methyl-propan-2-ol

3: (i) KOH, HOCH₂CH₂OH, (ii) (decarboxylation)

4: HCl

With hydrogenchloride; potassium hydroxide; In tert-butyl alcohol;

Reference yield:

dimethyl tetradecylpropanedioate (41240-57-7) → Methyl-4-methoxycarbonyloctadecanoat (29238-07-1)

Guidance literature:

Multi-step reaction with 3 steps

1: KOH / 2-methyl-propan-2-ol

2: (i) KOH, HOCH₂CH₂OH, (ii) (decarboxylation)

3: HCl

With hydrogenchloride; potassium hydroxide; In tert-butyl alcohol;

upstream raw materials:

methanol

2-tetradecyl-glutaric acid

1-tetradecene

Dimethyl glutarate

Downstream raw materials:

2-tetradecyl-glutaric acid

Refernces