1F-Fructofuranosylnystose

Base Information

• Chemical Name: 1F-Fructofuranosylnystose
• CAS No.: 59432-60-9
• Molecular Formula: C30H52 O26
• Molecular Weight: 828.727
• UNII: 0V2S93VI5J
• DSSTox Substance ID: DTXSID60974839
• Nikkaji Number: J412.116C
• Wikidata: Q27237281
• Mol file: 59432-60-9.mol

Synonyms:1F-fructofuranosylnystose

Chemical Property of 1F-Fructofuranosylnystose

Chemical Property:

• Boiling Point: 1227.3±65.0 °C(Predicted)
• PKA: 12.76±0.70(Predicted)
• PSA: 426.98000
• Density: 1.87±0.1 g/cm3(Predicted)
• LogP: -11.91820
• XLogP3: -9.2
• Hydrogen Bond Donor Count: 17
• Hydrogen Bond Acceptor Count: 26
• Rotatable Bond Count: 17
• Exact Mass: 828.27468176
• Heavy Atom Count: 56
• Complexity: 1270

Purity/Quality:

≥98% ^*data from raw suppliers

1,1,1-Kestopentaose ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C1C(C(C(C(O1)OC2(C(C(C(O2)CO)O)O)COC3(C(C(C(O3)CO)O)O)COC4(C(C(C(O4)CO)O)O)COC5(C(C(C(O5)CO)O)O)CO)O)O)O)O
• Isomeric SMILES: C([C@@H]1[C@H]([C@@H]([C@H]([C@H](O1)O[C@]2([C@H]([C@@H]([C@H](O2)CO)O)O)CO[C@]3([C@H]([C@@H]([C@H](O3)CO)O)O)CO[C@]4([C@H]([C@@H]([C@H](O4)CO)O)O)CO[C@]5([C@H]([C@@H]([C@H](O5)CO)O)O)CO)O)O)O)O
• Uses: 1,1,1-Kestopentaose is a fructan found in the taproot of Cichorium intybus and are degraded by fructan exohydrolases. 1,1,1-Kestopentaose is biologically produced from inulin by yeast.

Technology Process of 1F-Fructofuranosylnystose

There total 8 articles about 1F-Fructofuranosylnystose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.2%

Sucrose (57-50-1) → 1-fructofuranosylnystose (59432-60-9) + D-glucose (50-99-7) + 1-kestose (470-69-9) + nystose (13133-07-8)

Guidance literature:

With Aspergillus niger ATCC 20611 FopA(A₁₇₈P)-overexpression strain; In aq. buffer; at 50 ℃; for 5h; pH=5.5; Reagent/catalyst; Time; Microbiological reaction;

DOI:10.1016/j.jbiotec.2017.03.021

Reference yield:

sucrose (57-50-1) → D-Fructose (57-48-7,18875-34-8) + 1-fructofuranosylnystose (59432-60-9) + D-glucose (50-99-7) + 1-kestose (470-69-9) + nystose (13133-07-8)

Guidance literature:

With Aspergillus flavus NFCCI 2364 culture filtrate; In aq. buffer; at 55 ℃; for 24h; pH=5.5; Reagent/catalyst; Time; Microbiological reaction;

DOI:10.1016/j.molcatb.2013.07.008

Reference yield:

inulin → 5-hydroxymethyl-2-furfuraldehyde (67-47-0) + D-Fructose (57-48-7,18875-34-8) + 1-fructofuranosylnystose (59432-60-9) + α-D-fructofuranosyl-β-D-fructofuranosyl-(1,2':2,3')-dianhydride (81129-73-9) + 1-kestose (470-69-9) + nystose (13133-07-8)

Guidance literature:

With water; citric acid; at 50 - 95 ℃; for 0.25 - 0.75h; pH=1.75 - 3.75;

upstream raw materials:

Sucrose

sucrose

Downstream raw materials:

D-fructose

nystose

Refernces

• 1、 Zhang, Jing,Liu, Caixia,Xie, Yijia,Li, Ning,Ning, Zhanguo,Du, Na,Huang, Xirong,Zhong, Yaohua. "Enhancing fructooligosaccharides production by genetic improvement of the industrial fungus Aspergillus niger ATCC 20611". . p. 25 - 33. Retrieved 2017/04/06.
• 2、 Tian, Feng,Khodadadi, Maryam,Karboune, Salwa. "Optimization of levansucrase/endo-inulinase bi-enzymatic system for the production of fructooligosaccharides and oligolevans from sucrose". . p. 85 - 93. Retrieved 2014/12/10.