7-Octenoic acid ethyl ester

Base Information

• Chemical Name: 7-Octenoic acid ethyl ester
• CAS No.: 35194-38-8
• Molecular Formula: C10H18O2
• Molecular Weight: 170.252
• Hs Code.: 2918999090
• Mol file: 35194-38-8.mol

Synonyms:7-Octenoic acid ethyl ester;Ethyloct-7-enoate97%

Chemical Property of 7-Octenoic acid ethyl ester

Chemical Property:

• Vapor Pressure: 0.192mmHg at 25°C
• Boiling Point: 210.5°C at 760 mmHg
• Flash Point: 79.9°C
• PSA: 26.30000
• Density: 0.885g/cm³
• LogP: 2.68600

Purity/Quality:

99% ^*data from raw suppliers

Ethyl oct-7-enoate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 7-Octenoic acid ethyl ester

There total 9 articles about 7-Octenoic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

ethanol (64-17-5) + oct-7-enoic acid (18719-24-9) → ethyl oct-7-enoate (35194-38-8)

Guidance literature:

With sulfuric acid; at 100 ℃; for 0.166667h; Microwave irradiation;

DOI:10.1002/anie.201403537

Reference yield: 90.0%

Allyl acetate (591-87-7) + ethyl 5-bromovalerate (14660-52-7) → ethyl oct-7-enoate (35194-38-8)

Guidance literature:

Allyl acetate; With manganese; trifluoroacetic acid; cobalt(II) bromide; In acetonitrile; at 20 ℃; for 0.0833333h;

ethyl 5-bromovalerate; With pyridine; In acetonitrile; at 80 ℃;

DOI:10.1002/anie.201104390

Reference yield: 51.0%

ethyl 2-cyanooct-7-enoate (91340-22-6) → ethyl oct-7-enoate (35194-38-8)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; samarium diiodide; In tetrahydrofuran; Ambient temperature;

DOI:10.1016/0040-4039(95)01606-I

upstream raw materials:

(5-ethoxy-5-oxopentyl)zinc(II) iodide

allyl alcohol

ethyl 2-cyanooct-7-enoate

ethyl 2-(pyrimidin-2-ylsulfonyl)oct-7-enoate

Refernces

• 1、 Qian, Xin,Auffrant, Audrey,Felouat, Abdellah,Gosmini, Corinne. "Cobalt-catalyzed reductive allylation of alkyl halides with allylic acetates or carbonates". supporting information; experimental part. p. 10402 - 10405. Retrieved 2011/12/03.
• 2、 Kang,Hong,Cho,Koh. "Reductive decyanation of α-cyano and α-alkoxycarbonyl substituted nitriles promoted by samarium(II) iodide". . p. 7661 - 7664. Retrieved 2007/10/02.