4-ACETOXYBUTYL ZINC BROMIDE

Base Information

• Chemical Name: 4-ACETOXYBUTYL ZINC BROMIDE
• CAS No.: 737797-42-1
• Molecular Formula: C₆H₁₁BrO₂Zn
• Molecular Weight: 260.446
• Mol file: 737797-42-1.mol

Synonyms:4-ACETOXYBUTYL ZINC BROMIDE

Chemical Property of 4-ACETOXYBUTYL ZINC BROMIDE

Chemical Property:

• Flash Point: 1 °F
• Density: 0.985 g/mL at 25 °C(lit.)

Purity/Quality:

98%Min ^*data from raw suppliers

4-Acetoxybutylzincbromide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xn
• Statements: 14-19-22-36/37/38
• Safety Statements: 16-26-33-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-ACETOXYBUTYL ZINC BROMIDE

There total 1 articles about 4-ACETOXYBUTYL ZINC BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-Bromobutyl acetate (4753-59-7) + zinc (7440-66-6) → (4-acetoxybut-1-yl)zinc(II) bromide (737797-42-1)

Guidance literature:

zinc; at 20 ℃; for 0.0833333h; Glovebox; Inert atmosphere;

4-Bromobutyl acetate; at 80 ℃; for 16h; Glovebox; Inert atmosphere;

DOI:10.1039/c6cy00331a

Reference yield:

chloro-trimethyl-silane (75-77-4) + 3-methylcyclohexen-2-one (1193-18-6) + (4-acetoxybut-1-yl)zinc(II) bromide (737797-42-1) → C16H32O3Si

Guidance literature:

(4-acetoxybut-1-yl)zinc(II) bromide; With copper(I) bromide dimethylsulfide complex; In N,N-dimethyl acetamide; at 0 ℃; for 0.166667h; Schlenk technique; Inert atmosphere;

chloro-trimethyl-silane; 3-methylcyclohexen-2-one; In N,N-dimethyl acetamide; at 0 - 23 ℃; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.joc.8b02201

upstream raw materials:

4-Bromobutyl acetate

zinc

Refernces

• 1、 Paeth, Matthew,Tyndall, Sam B.,Chen, Liang-Yu,Hong, Jia-Cheng,Carson, William P.,Liu, Xingwu,Sun, Xiaodong,Liu, Jinjia,Yang, Kundi,Hale, Elizabeth M.,Tierney, David L.,Liu, Bin,Cao, Zhi,Cheng, Mu-Jeng,Goddard, William A.,Liu, Wei. "Csp3-Csp3 Bond-Forming Reductive Elimination from Well-Defined Copper(III) Complexes". supporting information. p. 3153 - 3159. Retrieved 2019/03/06.
• 2、 Price, Gregory A.,Bogdan, Andrew R.,Aguirre, Ana L.,Iwai, Toshiyuki,Djuric, Stevan W.,Organ, Michael G.. "Continuous flow Negishi cross-couplings employing silica-supported: Pd-PEPPSI - IPr precatalyst". . p. 4733 - 4742. Retrieved 2016/07/11.