1-methyl-4,5-dihydro-1H-1,2,3-triazole

Base Information

• Chemical Name: 1-methyl-4,5-dihydro-1H-1,2,3-triazole
• CAS No.: 136911-37-0
• Molecular Formula: C3H7N3
• Molecular Weight: 85.1087
• Mol file: 136911-37-0.mol

Synonyms:

Chemical Property of 1-methyl-4,5-dihydro-1H-1,2,3-triazole

Chemical Property:

• Vapor Pressure: 68.3mmHg at 25°C
• Boiling Point: 85.8°Cat760mmHg
• Flash Point: 5.7°C
• Density: 1.19g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-methyl-4,5-dihydro-1H-1,2,3-triazole

There total 1 articles about 1-methyl-4,5-dihydro-1H-1,2,3-triazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(2-chloroethyl)-3-methyl-3-carbethoxytriazene (113274-29-6) → ethanol (64-17-5) + 1-methyltriazoline (136911-37-0) + methylamine (74-89-5)

Guidance literature:

With lysine buffer; sodium perchlorate; In acetonitrile; at 70 ℃; Rate constant; variation of pH, solvent deuterium isotope effect;

DOI:10.1021/jo00050a016

Reference yield:

1-methyltriazoline (136911-37-0) → N-methylaziridine (1072-44-2) + (2-hydroxyethyl)(methyl)amine (109-83-1) + acetaldehyde (75-07-0,9002-91-9) + methylamine (74-89-5)

Guidance literature:

With water; at 25 ℃; Rate constant; Product distribution; Mechanism; pH 10.75 (lysine buffer); other solvent, other pH (other buffers), H/D isotope effect;

DOI:10.1021/jo00060a027

upstream raw materials:

1-(2-chloroethyl)-3-methyl-3-carbethoxytriazene

Downstream raw materials:

N-methylaziridine

(2-hydroxyethyl)(methyl)amine

acetaldehyde

methylamine

Refernces