2-(tert-butyldimethylsiloxy)methylcyclohex-2-en-1-yl 2,2,2-trichloroethyl carbonate

Base Information

Chemical Name:2-(tert-butyldimethylsiloxy)methylcyclohex-2-en-1-yl 2,2,2-trichloroethyl carbonate
CAS No.:1270092-33-5
Molecular Formula:C₁₆H₂₇Cl₃O₄Si
Molecular Weight:417.832
Hs Code.:

Synonyms:2-(tert-butyldimethylsiloxy)methylcyclohex-2-en-1-yl 2,2,2-trichloroethyl carbonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(tert-butyldimethylsiloxy)methylcyclohex-2-en-1-yl 2,2,2-trichloroethyl carbonate

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Technology Process of 2-(tert-butyldimethylsiloxy)methylcyclohex-2-en-1-yl 2,2,2-trichloroethyl carbonate

There total 2 articles about 2-(tert-butyldimethylsiloxy)methylcyclohex-2-en-1-yl 2,2,2-trichloroethyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: C₁₃H₂₆O₂Si

: 17341-93-4
2,2,2-Trichloroethyl chloroformate

: 1270092-33-5
2-(tert-butyldimethylsiloxy)methylcyclohex-2-en-1-yl 2,2,2-trichloroethyl carbonate

Guidance literature:: With pyridine; In dichloromethane; at 0 ℃; for 1h; Inert atmosphere;
DOI:10.1002/asia.201000697

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1270092-33-5
2-(tert-butyldimethylsiloxy)methylcyclohex-2-en-1-yl 2,2,2-trichloroethyl carbonate

Guidance literature:: Multi-step reaction with 2 steps

1: 1H-imidazole / tetrahydrofuran / 1.5 h / 0 °C / Inert atmosphere

2: pyridine / dichloromethane / 1 h / 0 °C / Inert atmosphere

With pyridine; 1H-imidazole; In tetrahydrofuran; dichloromethane;
DOI:10.1002/asia.201000697

Reference yield:

: 1270092-33-5
2-(tert-butyldimethylsiloxy)methylcyclohex-2-en-1-yl 2,2,2-trichloroethyl carbonate

: 1024-38-0
N-(2-bromophenyl)-4-methylbenzenesulfonamide

: 92011-93-3
2-<<(tert-butyldimethylsilyl)oxy>methyl>-1,3-cyclohexadiene

: (R)-N-(2-bromophenyl)-N-(2-(2-tert-butyldimethylsiloxy)methylcyclohex-2-en-1-yl)(4-methylbenzene)sulfonamide

: 350677-95-1
(S)-N-(2-bromophenyl)-N-(2-(2-tert-butyldimethylsiloxy)methylcyclohex-2-en-1-yl)(4-methylbenzene)sulfonamide

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; (R)-2,2'-bis(diphenylphosphinyloxy)-3,3',5,5',6,6'-hexamethyl-1,1'-biphenyl; In N,N-dimethyl-formamide; at 25 ℃; for 24h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/asia.201000697