[RuClCp(3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)(PPh₃)]*(OSO₂CF₃)

Base Information

• Chemical Name: [RuClCp(3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)(PPh₃)]*(OSO₂CF₃)
• CAS No.: 946088-18-2
• Molecular Formula: CF₃O₃S*C₃₀H₃₇ClN₃P₂Ru
• Molecular Weight: 787.185

Synonyms:[RuClCp(3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)(PPh₃)]*(OSO₂CF₃)

Chemical Property of [RuClCp(3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)(PPh₃)]*(OSO₂CF₃)

Chemical Property:

Purity/Quality:

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Technology Process of [RuClCp(3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)(PPh₃)]*(OSO₂CF₃)

There total 5 articles about [RuClCp(3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)(PPh₃)]*(OSO₂CF₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) + 1,3-dimethyl-5-aza-1,3-diazonia-7-phosphatricyclo[3.3.1.1(3,7)]decane trifluoromethanesulfonate + water (7732-18-5) → [RuClCp(3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)(PPh3)]*(OSO2CF3) (946088-18-2)

Guidance literature:

In acetone; byproducts: CH2O, CF3SO3H, PPh3; Sonication; (Ar); (C6H12N3P(CH3)2)(O3SCF3)2 added to an acetone suspn. of Ru complex, refluxed for 5 h, concd., n-hexane added, sonicated for 5 min, decanted, dried (vac.), dissolved in H2O in MeOH, refluxed for 1 h; concd., n-hexane added, stirred on an ice bath for 10 min, filtered, washed (Et2O), dried (vac.);

DOI:10.1039/c0dt00571a

Reference yield: 72.0%

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) + 1,3-dimethyl-5-aza-1,3-diazonia-7-phosphatricyclo[3.3.1.1(3,7)]decane trifluoromethanesulfonate → [(C5H5)RuCl(PPh3)(3,7-H-3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)]O3SCF3 (946088-18-2)

Guidance literature:

In acetone; (Ar); std. Schlenk technique; ligand was added to soln. of Ru complex inacetone; mixt. was refluxed for 6 h; evapd.; dissolved in MeOH/H2O (9/1); refluxed for 2 h; cooled; evapd.; Et2O added; filtered; washed (MeOH, Et2O); dried (vac.); elem. anal.;

DOI:10.1021/ic070168m

Reference yield: 62.0%

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) + [3,7-H-3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane]O3SCF3 → [(C5H5)RuCl(PPh3)(3,7-H-3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)]O3SCF3 (946088-18-2)

Guidance literature:

In acetone; (Ar); std. Schlenk technique; soln. of ligand and Ru complex in acetone was refluxed for 2 h; concd.; EtOH added; filtered; washed (Et2O); dried (vac.);

DOI:10.1021/ic070168m

upstream raw materials:

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

water

[RuClCp(PPh3)-μ-3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane-1κP:2κ2N,N′-CoCl2]

silver trifluoromethanesulfonate

Downstream raw materials:

[RuClCp(PPh3)-μ-3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane-1κP:2κ2N,N'-Co(acetylacetonato-κ2O,O')2]*H2O

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