1,1'-bis[bis(4-methoxyphenyl)phosphino]ferrocene

Base Information

Chemical Name:1,1'-bis[bis(4-methoxyphenyl)phosphino]ferrocene
CAS No.:70227-89-3
Molecular Formula:C₃₈H₃₆FeO₄P₂
Molecular Weight:674.496
Hs Code.:

Synonyms:1,1'-bis[bis(4-methoxyphenyl)phosphino]ferrocene

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Chemical Property of 1,1'-bis[bis(4-methoxyphenyl)phosphino]ferrocene

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Technology Process of 1,1'-bis[bis(4-methoxyphenyl)phosphino]ferrocene

There total 2 articles about 1,1'-bis[bis(4-methoxyphenyl)phosphino]ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: 102-54-5,55404-68-7
ferrocene

: 13685-30-8
chlorobis(4-methoxyphenyl)phosphane

: 70227-89-3
1,1'-bis[bis(4-methoxyphenyl)phosphino]ferrocene

Guidance literature:: With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; hexane; to suspn. ferrocene in hexane BuLi in hexane and TMEDA were added and stirred at 60°C for 1 h, heating bath was removed, THF was added, suspn. was cooled to -50°C, soln. (4-MeOC6H4)2PCl was added and stirred at room temp. overnight; Et2O was added, soln. was filtered, filtrate was washed with dilute HCl,saturated NaHCO3, and H2O, dried over Na2SO4, and chromed. on silica (h exane/Et2O 1:1);
DOI:10.1021/om020680+

Reference yield: 39.0%

: 1,1’-bis-(dichlorophosphine)ferrocene

: 13139-86-1
4-methoxyphenyl magnesium bromide

: 70227-89-3
1,1'-bis[bis(4-methoxyphenyl)phosphino]ferrocene

Guidance literature:: Inert atmosphere;
DOI:10.1021/acs.organomet.8b00484

Reference yield: 94.0%

: 70227-89-3
1,1'-bis[bis(4-methoxyphenyl)phosphino]ferrocene

: 475501-70-3
[PdCl(η3-deuterio-1,1-dimethylallyl)]2

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 475501-80-5
[Pd(η3-deuterio-1,1-dimethylallyl)(1,1'-bis[di(4-methoxyphenyl)phosphino]ferrocene)][B(C6H3-3,5-(CF3)2)4]

Guidance literature:: In methanol; mixt. Pd complex and bisphosphine was dissolved in MeOH, Na(B(C6H3-3,5-(CF3)2)4) in MeOH was added, soln. was allowed to stand for 30 min at room temp. and at 0°C overnight; soln. was evapd. to dryness, residue was chromed. on silica (CHCl3); elem. anal.;
DOI:10.1021/om020680+