dimethyl 2,3-dimethoxybutanedioate

Base Information

• Chemical Name: dimethyl 2,3-dimethoxybutanedioate
• CAS No.: 72719-00-7
• Molecular Formula: C₈H₁₄O₆
• Molecular Weight: 206.196
• Mol file: 72719-00-7.mol

Synonyms:dimethyl 2,3-dimethoxybutanedioate

Chemical Property of dimethyl 2,3-dimethoxybutanedioate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dimethyl 2,3-dimethoxybutanedioate

There total 17 articles about dimethyl 2,3-dimethoxybutanedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

dimethyl L-tartrate (608-68-4) + methyl iodide (74-88-4) → (R,R)-2,3-dimethoxy-succinic acid dimethyl ester (62138-50-5,62182-40-5,72719-00-7,56145-21-2)

Guidance literature:

With silver(l) oxide; In diethyl ether;

DOI:10.1080/10242430210704

Reference yield: 99.0%

Dimethyl D-tartrate (13171-64-7) + methyl iodide (74-88-4) → dimethyl (O,O'-dimethyl)-L-tartrate (56145-21-2,62138-50-5,62182-40-5,72719-00-7)

Guidance literature:

With silver(l) oxide;

DOI:10.1002/chem.201102902

Reference yield: 19.5%

triethylsilane (617-86-7) + methyl methoxybromoacetate (5193-96-4) → dimethyl 2,3-dimethoxybutanedioate (72719-00-7) + t-butyl bromide (507-19-7) + triethyl-bromo-silane (1112-48-7) + tert-butyl alcohol (75-65-0)

Guidance literature:

With di-tert-butyl peroxide; In chlorobenzene; at 30 ℃; for 0.1h; Product distribution; Irradiation;

upstream raw materials:

triethylsilane

methyl methoxybromoacetate

Dimethyl D-tartrate

methyl iodide

Downstream raw materials:

methyl (3S,4S)-3,4-dimethoxy-1-{[(3S,4S)-3,4-dimethoxy-1-{[(3S,4S)-3,4-dimethoxy-1-{[(3S,4S)-3,4-dimethoxy-1-(benzyloxycarbonylamino)cyclopentyl]carbonylamino}cyclopentyl]carbonylamino}cyclopentyl]carbonylamino}cyclopentanecarboxylate

(3S,4S)-1-benzyloxycarbonylamino-3,4-(dimethoxy)cyclopentanecarboxylic acid

methyl (3S,4S)-1-benzyloxycarbonylamino-3,4-(dimethoxy)cyclopentanecarboxylate

H-(S,S)-Ac₅cdOM-OMe

Refernces

• 1、 Yoshida, Kazuhiro,Osawa, Shuichi,Monde, Kenji,Watanabe, Masataka,Harada, Nobuyuki. "Absolute stereochemistry of chiral, C60 fullerene bis-adducts". . p. 23 - 32. Retrieved 2007/10/03.
• 2、 Izquierdo, Isidoro,Plaza, Maria T.. "Synthesis of 4-octuloses from a derivative of D-fructose". . p. 303 - 315. Retrieved 2007/10/03.