N,N'-bis[(2-aminoethyl)-2-pyridyl]-1,2-bis(4-tolylimino)ethane-1,2-diamine

Base Information

• Chemical Name: N,N'-bis[(2-aminoethyl)-2-pyridyl]-1,2-bis(4-tolylimino)ethane-1,2-diamine
• CAS No.: 337525-13-0
• Molecular Formula: C₃₀H₃₂N₆
• Molecular Weight: 476.624
• Mol file: 337525-13-0.mol

Synonyms:N,N'-bis[(2-aminoethyl)-2-pyridyl]-1,2-bis(4-tolylimino)ethane-1,2-diamine

Chemical Property of N,N'-bis[(2-aminoethyl)-2-pyridyl]-1,2-bis(4-tolylimino)ethane-1,2-diamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of N,N'-bis[(2-aminoethyl)-2-pyridyl]-1,2-bis(4-tolylimino)ethane-1,2-diamine

There total 1 articles about N,N'-bis[(2-aminoethyl)-2-pyridyl]-1,2-bis(4-tolylimino)ethane-1,2-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

2-(aminoethyl)pyridine (2706-56-1) + N,N'-di(p-tolyl)oxaldiimidoyl dichloride (7472-70-0) → N,N'-bis[(2-aminoethyl)-2-pyridyl]-1,2-bis(4-tolylimino)ethane-1,2-diamine (337525-13-0)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 50 ℃; for 1h;

DOI:10.1002/1099-0682(200103)2001:3<805::AID-EJIC805>3.0.CO;2-2

Reference yield: 62.0%

methanol (67-56-1) + Cu(CH3COO)2H2O + N,N'-bis[(2-aminoethyl)-2-pyridyl]-1,2-bis(4-tolylimino)ethane-1,2-diamine (337525-13-0) → bis(methanol)bis(acetato)(N,N'-bis[(2-aminoethyl)-2-pyridyl]-1,2-bis(4-tolylimino)ethane-1,2-diaminato)dicurpate(II)

Guidance literature:

With ether; In methanol; under inert atm.; mixt. of solns. stirred for 2 h at 50°C, filtered, solvent of filtrate removed in vacuo, ether added to residue of filtrate, pptd.; ppt. filtered, dried in vacuo, recrystd. from MeOH or H2O/MeOH (1:1); elem. anal.;

DOI:10.1002/1099-0682(200103)2001:3<805::AID-EJIC805>3.0.CO;2-2

Reference yield: 52.0%

dichloro bis(acetonitrile) palladium(II) (21264-30-2,90243-59-7,14592-56-4) + N,N'-bis[(2-aminoethyl)-2-pyridyl]-1,2-bis(4-tolylimino)ethane-1,2-diamine (337525-13-0) → dicloro[N,N'-bis((2-aminoethyl)-2-pyridyl)-1,2-bis(4-tolylimino)ethane-1,2-diaminato]dipalladate(II) (337525-27-6)

Guidance literature:

In tetrahydrofuran; under inert atm.; stirred for 24 h at 20°C, pptd.; ppt. filtered, washed (THF), dried in vacuo; elem. anal.;

DOI:10.1002/1099-0682(200103)2001:3<805::AID-EJIC805>3.0.CO;2-2

upstream raw materials:

2-(aminoethyl)pyridine

N,N'-di(p-tolyl)oxaldiimidoyl dichloride

Downstream raw materials:

dicloro[N,N'-bis((2-aminoethyl)-2-pyridyl)-1,2-bis(4-tolylimino)ethane-1,2-diaminato]dipalladate(II)