(η5-cyclopentadienyl)bis(triphenylphosphane)(η1-tetraphosphrus)osmium(II) triflate

Base Information

Chemical Name:(η5-cyclopentadienyl)bis(triphenylphosphane)(η1-tetraphosphrus)osmium(II) triflate
CAS No.:1232174-52-5
Molecular Formula:CF₃O₃S*C₄₁H₃₅OsP₆
Molecular Weight:1052.84
Hs Code.:

Synonyms:(η5-cyclopentadienyl)bis(triphenylphosphane)(η1-tetraphosphrus)osmium(II) triflate

Suppliers and Price of (η5-cyclopentadienyl)bis(triphenylphosphane)(η1-tetraphosphrus)osmium(II) triflate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (η5-cyclopentadienyl)bis(triphenylphosphane)(η1-tetraphosphrus)osmium(II) triflate

Chemical Property:

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Technology Process of (η5-cyclopentadienyl)bis(triphenylphosphane)(η1-tetraphosphrus)osmium(II) triflate

There total 1 articles about (η5-cyclopentadienyl)bis(triphenylphosphane)(η1-tetraphosphrus)osmium(II) triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: phosphorus

: 79151-48-7
(η5-cyclopentadienyl)bis(triphenylphosphane)chloridoosmium(II)

: 2923-28-6
silver trifluoromethanesulfonate

: 1232174-52-5
(η5-cyclopentadienyl)bis(triphenylphosphane)(η1-tetraphosphrus)osmium(II) triflate

Guidance literature:: In tetrahydrofuran; dichloromethane; byproducts: AgCl; (Ar), AgOTf added to soln. of Os complex (1:1) in CH2Cl2/THF 1:1 v/v, stirred at room temp. for 2 h, filtered, filtrate added to P4 (1.4 equiv.)in THF, stirred for 1 h at room temp.; evapd.(vac.), washed (toluene, pentane), dried, recrystd.(CHCl3/n-hexane), elem. anal.;
DOI:10.1002/ejic.200900884

Reference yield: 80.0%

: 113322-93-3
(η5-cyclopentadienyl)bis(triphenylphosphane)(triflate)ruthenium(II)

: 1232174-52-5
(η5-cyclopentadienyl)bis(triphenylphosphane)(η1-tetraphosphrus)osmium(II) triflate

: (η5-cyclopentadienyl)bis(triphenylphosphane)ruthenium(II)(μ,η1:1-tetraphosphorus)(η5-cyclopentadienyl)bis(triphenylphosphane)osmium(II) triflate

Guidance literature:: In tetrahydrofuran; dichloromethane; (Ar), stoich., soln. of Ru complex in CH2Cl2 added to Os complex in CH2Cl2/THF 1:1 v/v, stirred at room temp. for 30 min.; evapd.(vac.), recrystd.(CHCl3/n-hexane), elem. anal.;
DOI:10.1002/ejic.200900884

Reference yield: 20.0%

: 1232174-52-5
(η5-cyclopentadienyl)bis(triphenylphosphane)(η1-tetraphosphrus)osmium(II) triflate

: 7732-18-5
water

: 13598-36-2
phosphonic Acid

: 1232174-60-5
(η5-cyclopentadienyl)bis(triphenylphosphane)(phosphine)osmium(II) triflate

: (η5-cyclopentadienyl)bis(triphenylphosphane)(phosphorous acid)osmium(II) triflate

: 6303-21-5
hypophosphorous acid

Guidance literature:: In tetrahydrofuran; (Ar), Os complex treated with 100 equiv. of H2O in THF, stirred at room temp. for 1 d; evapd.(vac.);
DOI:10.1002/ejic.200900884