(η5-cyclopentadienyl)bis(triphenylphosphane)(phosphine)osmium(II) triflate

Base Information

Chemical Name:(η5-cyclopentadienyl)bis(triphenylphosphane)(phosphine)osmium(II) triflate
CAS No.:1232174-60-5
Molecular Formula:CF₃O₃S*C₄₁H₃₈OsP₃
Molecular Weight:962.944
Hs Code.:

Synonyms:(η5-cyclopentadienyl)bis(triphenylphosphane)(phosphine)osmium(II) triflate

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Chemical Property of (η5-cyclopentadienyl)bis(triphenylphosphane)(phosphine)osmium(II) triflate

Chemical Property:

Purity/Quality:

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Technology Process of (η5-cyclopentadienyl)bis(triphenylphosphane)(phosphine)osmium(II) triflate

There total 3 articles about (η5-cyclopentadienyl)bis(triphenylphosphane)(phosphine)osmium(II) triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 79151-48-7
(η5-cyclopentadienyl)bis(triphenylphosphane)chloridoosmium(II)

: 2923-28-6
silver trifluoromethanesulfonate

: 7803-51-2
phosphan

: 1232174-60-5
(η5-cyclopentadienyl)bis(triphenylphosphane)(phosphine)osmium(II) triflate

Guidance literature:: In tetrahydrofuran; dichloromethane; byproducts: AgCl; gas PH3 gentlu bubbled for 5 min through soln. of Os complex and AgOTf in CH2Cl2/THF 1:1 v/v, stirred at room temp. for 1 h; filtered, evapd.(vac.), recrystd.(CH2Cl2/n-hexane), elem. anal.;
DOI:10.1002/ejic.200900884

Reference yield: 20.0%

: 1232174-52-5
(η5-cyclopentadienyl)bis(triphenylphosphane)(η1-tetraphosphrus)osmium(II) triflate

: 7732-18-5
water

: 13598-36-2
phosphonic Acid

: 1232174-60-5
(η5-cyclopentadienyl)bis(triphenylphosphane)(phosphine)osmium(II) triflate

: (η5-cyclopentadienyl)bis(triphenylphosphane)(phosphorous acid)osmium(II) triflate

: 6303-21-5
hypophosphorous acid

Guidance literature:: In tetrahydrofuran; (Ar), Os complex treated with 100 equiv. of H2O in THF, stirred at room temp. for 1 d; evapd.(vac.);
DOI:10.1002/ejic.200900884

Reference yield:

: (η5-cyclopentadienyl)bis(triphenylphosphane)ruthenium(II)(μ,η1:1-tetraphosphorus)(η5-cyclopentadienyl)bis(triphenylphosphane)osmium(II) triflate

: 7732-18-5
water

: 13598-36-2
phosphonic Acid

: (η5-cyclopentadienyl)bis(triphenylphosphane)(hypophosphorous acid)ruthenium(II)

: (η5-cyclopentadienyl)bis(triphenylphosphane)(hypophosphorous acid)osmium(II)

: 1232174-60-5
(η5-cyclopentadienyl)bis(triphenylphosphane)(phosphine)osmium(II) triflate

: (η5-cyclopentadienyl)bis(triphenylphosphane)(phosphorous acid)osmium(II) triflate

Guidance literature:: In tetrahydrofuran; further products; (Ar), Os complex treated with 100 equiv. of H2O in THF, stirred at room temp. for 1 h; evapd.(vac.), NMR;
DOI:10.1002/ejic.200900884