4-methoxy-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide

Base Information

• Chemical Name: 4-methoxy-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide
• CAS No.: 1377585-48-2
• Molecular Formula: C₁₅H₁₅NO₃S
• Molecular Weight: 289.355
• Mol file: 1377585-48-2.mol

Synonyms:4-methoxy-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide

Chemical Property of 4-methoxy-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 4-methoxy-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide

There total 24 articles about 4-methoxy-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

4-methoxy-benzaldehyde (123-11-5) + S-methyl-S-phenylsulfoximine (4381-25-3) → 4-methoxy-N-(methyl(oxo)(phenyl)-λ6-sulfanylidene)benzamide (1377585-48-2)

Guidance literature:

With tert.-butylhydroperoxide; dipotassium peroxodisulfate; In acetonitrile; at 20 ℃; for 12h; Irradiation;

DOI:10.1007/s11426-019-9499-5

Reference yield: 91.0%

p-methylanizole (104-93-8) + S-methyl-S-phenylsulfoximine (4381-25-3) → 4-methoxy-N-(methyl(oxo)(phenyl)-λ6-sulfanylidene)benzamide (1377585-48-2)

Guidance literature:

With tert.-butylhydroperoxide; copper(l) iodide; water; In neat (no solvent); at 80 ℃; for 20h; Schlenk technique;

DOI:10.1080/00397911.2017.1318444

Reference yield: 91.0%

carbon monoxide (201230-82-2) + para-iodoanisole (696-62-8) + S-methyl-S-phenylsulfoximine (4381-25-3) → 4-methoxy-N-(methyl(oxo)(phenyl)-λ6-sulfanylidene)benzamide (1377585-48-2)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 24h;

DOI:10.1039/c6ra05334c

upstream raw materials:

racemic methyl phenyl sulfoxide

S-methyl-S-phenylsulfoximine

4-methoxybenzoic acid

4-methoxy-benzaldehyde

Downstream raw materials:

N-[2-hydroxy-4-methoxybenzoyl]-S-methyl-S-phenylsulfoximine

N-[2-(4'-methylbenzenesulfonamido)-4-methoxybenzoyl]-S-methyl-S-phenylsulfoximine

N-[2,6-di(4'-methylbenzenesulfonamido)-4-methoxybenzoyl]-S-methyl-S-phenylsulfoximine

N-[2-acetoxy-4-methoxybenzoyl]-S-methyl-S-phenylsulfoximine