[5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-(([(tert-butyl)(dimethyl)silyl]oxy)methyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

Base Information

Chemical Name:[5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-(([(tert-butyl)(dimethyl)silyl]oxy)methyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)
CAS No.:866321-85-9
Molecular Formula:C₆₁H₇₂N₄OSiZn
Molecular Weight:970.744
Hs Code.:

Synonyms:[5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-(([(tert-butyl)(dimethyl)silyl]oxy)methyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

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Chemical Property of [5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-(([(tert-butyl)(dimethyl)silyl]oxy)methyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

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Technology Process of [5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-(([(tert-butyl)(dimethyl)silyl]oxy)methyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

There total 1 articles about [5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-(([(tert-butyl)(dimethyl)silyl]oxy)methyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 220355-76-0
[5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

: 495402-49-8
2-[3-({[(tert-butyl)(dimethyl)silyl]oxy}methyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: [5,15-bis[3,5-di(tert-butyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

: 866321-85-9
[5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-(([(tert-butyl)(dimethyl)silyl]oxy)methyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

Guidance literature:: With Cs₂CO₃; H₂O; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; N2 atm.; to a soln. of complex in toluene borolane-compound, Pd(P(C6H5)3)4, Cs2CO3 and three drops of H2O were added, the mixt. was deoxygenatedby bubbling N2, heated to 140°C for 18 h, cooled to 25°C; filtered through Celite, evapd. in vac.; flash chromy. (silica gel; cyclohexane/CH2Cl2 8:2, 1% v/v (C2H5)3N), pptn. with methanol/H2O 95:5 from CHCl3-soln.;
DOI:10.1002/hlca.200590144

Reference yield: 80.0%

: 67-56-1
methanol

: 866321-85-9
[5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-(([(tert-butyl)(dimethyl)silyl]oxy)methyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

: 7732-18-5
water

: [5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-(hydroxymethyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

Guidance literature:: With (C₄H₉)4NF; In tetrahydrofuran; N2 atm.; several drops of 1 M soln. of (C4H9)4NF in THF were added at 0°C to a soln. of complex in THF, the mixt. was stirred for 30 min at 0°C and 1 h at 25°C; CHCl3 was added followed by H2O, the organic layer was washed with H2O, satd. aq. NaCl, dried (Na2SO4), evapd. in vac.; flash chromy. (silica gel; cyclohexane/CH2Cl2 1:1, 1% v/v (C2H5)3N), pptn. from CHCl3 by addn. of methanol/H2O 95:5; elem. anal.;
DOI:10.1002/hlca.200590144