chlorobis(4-methylphenyl)antimony

Base Information

• Chemical Name: chlorobis(4-methylphenyl)antimony
• CAS No.: 87856-04-0
• Molecular Formula: C₁₄H₁₄ClSb
• Molecular Weight: 339.468
• Mol file: 87856-04-0.mol

Synonyms:chlorobis(4-methylphenyl)antimony

Chemical Property of chlorobis(4-methylphenyl)antimony

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chlorobis(4-methylphenyl)antimony

There total 5 articles about chlorobis(4-methylphenyl)antimony which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

4-methylbenzenediazonium tetrafluoroborate (459-44-9) + antimony(III) chloride (10025-91-9) → tri(p-tolyl)antimony (5395-43-7) + dichloro(4-methylphenyl)stibine (87856-09-5) + chlorobis(4-methylphenyl)antimony (87856-04-0)

Guidance literature:

With zinc; In acetic acid; with zinc dust;

Reference yield: 8.0%

4-methylbenzenediazonium tetrafluoroborate (459-44-9) + antimony(III) chloride (10025-91-9) → tri(p-tolyl)antimony (5395-43-7) + chlorobis(4-methylphenyl)antimony (87856-04-0)

Guidance literature:

With zinc; In acetic anhydride;

Reference yield:

tri-p-tolylantimony dichloride (26508-67-8) → para-chlorotoluene (106-43-4) + chlorobis(4-methylphenyl)antimony (87856-04-0)

Guidance literature:

heating at 5-7 Torr; washing with petroleum ether and ethanol;

DOI:10.1039/JR9280000719

upstream raw materials:

antimony(III) chloride

tri(p-tolyl)antimony

4-methylbenzenediazonium tetrafluoroborate

antimony

Downstream raw materials:

4-p-tolylnonan-2-one

Os3(μ-SbPh2)(μ-Sb(C6H4Me-p)2)(CO)10

bis(4-methylphenyl)(phenylthio)stibine

bis(4-methylphenyl)[2-(phenylthio)phenyl]stibine

Refernces

• 1、 Nunn, Michael,Sowerby, D. Bryan,Wesolek, Denise M.. "THE PREPARATION OF PHENYL SUBSTITUTED ANTIMONY(III) AND ANTIMONY(V) CHLORIDES AND BROMIDES". . p. C45 - C46. Retrieved 2007/10/02.