Trimethylsilyl

Base Information

• Chemical Name: Trimethylsilyl
• CAS No.: 16571-41-8
• Deprecated CAS: 1223582-73-7
• Molecular Formula: C3H9 Si
• Molecular Weight: 73.19
• UNII: 9L70DJH2K0
• DSSTox Substance ID: DTXSID60870822,DTXSID90937119
• Nikkaji Number: J271.179F
• Wikidata: Q82913324
• Mol file: 16571-41-8.mol

Synonyms:Trimethylsilyl radical;Trimethylsilyl;16571-41-8;9L70DJH2K0;Trimsyl;Trimethylsilicon;MFCD00039791;Silyl, trimethyl-;C3H10Si;UNII-9L70DJH2K0;Trimethylsilyl radical (Me3Si);EINECS 213-603-0;C3H9Si;(CH3)3Si;DTXSID60870822;DTXSID90937119;AMY21899;ZAA14492

Chemical Property of Trimethylsilyl

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.37060
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 73.047351822
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metalloid Compounds (Silicon)
• Canonical SMILES: C[Si](C)C

Technology Process of Trimethylsilyl

There total 5 articles about Trimethylsilyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1,1,2,2,2-hexamethyldisilane (1450-14-2) → methyl radical (2229-07-4) + tetramethylsilane (75-76-3) + methane (34557-54-5,27936-85-2) + ethane (74-84-0) + trimethylsilan (993-07-7) + trimethylsilyl radical (16571-41-8)

Guidance literature:

under 14 Torr; Quantum yield; Product distribution; Mechanism; Irradiation; various additives;

DOI:10.1021/j100438a001

Reference yield:

1,1,1,2,2,2-hexamethyldisilane (1450-14-2) → trimethylsilan (993-07-7) + trimethylsilyl radical (16571-41-8)

Guidance literature:

With hydrogen; at 21.9 ℃; Rate constant; Thermodynamic data; activation energy; in addition the rate of disappearence of the trimethylsilyl radical was also estimated;

DOI:10.1021/j150657a024

Reference yield:

4--N,N'-dimethylbenzenamine (143143-29-7) → trimethylsilyl radical (16571-41-8) + 4-N,N-dimethylaminotriphenylmethyl radical (101059-99-8)

Guidance literature:

In hexane; at 20 ℃; Further Variations:; Solvents; Kinetics; Quantum yield; Flash photolysis;

DOI:10.1021/jo000023w

upstream raw materials:

1,1,1,2,2,2-hexamethyldisilane

2-phenylheptamethyltrisilane

4--N,N'-dimethylbenzenamine

1-{4-[(trimethylsilyl)methyl]phenyl}ethan-1-one

Downstream raw materials:

chloro-trimethyl-silane

pentyl

ethyl radical

trimethylsilyl bromide