(+)-phenylmethyl [(1S)-1-({[(1,1-dimethylethyl)(diphenyl)silyl]oxy}methyl)prop-2-en-1-yl]formylcarbamate

Base Information

Chemical Name:(+)-phenylmethyl [(1S)-1-({[(1,1-dimethylethyl)(diphenyl)silyl]oxy}methyl)prop-2-en-1-yl]formylcarbamate
CAS No.:1234693-04-9
Molecular Formula:C₂₉H₃₃NO₄Si
Molecular Weight:487.671
Hs Code.:

Synonyms:(+)-phenylmethyl [(1S)-1-({[(1,1-dimethylethyl)(diphenyl)silyl]oxy}methyl)prop-2-en-1-yl]formylcarbamate

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Chemical Property of (+)-phenylmethyl [(1S)-1-({[(1,1-dimethylethyl)(diphenyl)silyl]oxy}methyl)prop-2-en-1-yl]formylcarbamate

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Technology Process of (+)-phenylmethyl [(1S)-1-({[(1,1-dimethylethyl)(diphenyl)silyl]oxy}methyl)prop-2-en-1-yl]formylcarbamate

There total 1 articles about (+)-phenylmethyl [(1S)-1-({[(1,1-dimethylethyl)(diphenyl)silyl]oxy}methyl)prop-2-en-1-yl]formylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 862157-37-7
C₂₂H₂₈O₄Si

: 69261-49-0
benzyl formylcarbamate

: 1234693-04-9
(+)-phenylmethyl [(1S)-1-({[(1,1-dimethylethyl)(diphenyl)silyl]oxy}methyl)prop-2-en-1-yl]formylcarbamate

: 1315127-97-9
phenylmethyl ((2E)-4-{[(1,1-dimethylethyl)(diphenyl)silyl]oxy}but-2-en-1-yl)formylcarbamate

: (-)-phenylmethyl [(1S)-1-({[(1,1-dimethylethyl)(diphenyl)silyl]oxy}methyl)prop-2-en-1-yl]carbamate

Guidance literature:: With bis(1,5-cyclooctadiene)diiridium(I) dichloride; C₃₈H₃₄NO₄P; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine; In tetrahydrofuran; at 20 ℃; for 18h; enantioselective reaction; Inert atmosphere;
DOI:10.1002/chem.201100649

Reference yield: 94.0%

: 201230-82-2
carbon monoxide

: 1234693-04-9
(+)-phenylmethyl [(1S)-1-({[(1,1-dimethylethyl)(diphenyl)silyl]oxy}methyl)prop-2-en-1-yl]formylcarbamate

: 129986-67-0
N-methoxy-N-methyl-2-(triphenylphosphoranylidene)acetamide

: 1234693-24-3
C₃₄H₄₄N₂O₆Si

: 1234693-14-1
C₃₄H₄₂N₂O₆Si

Guidance literature:: With (acetylacetonato)dicarbonylrhodium (l); hydrogen; 6,6′-[(3,3′-di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(di-benzo[d,f][1,3,2]dioxaphosphepin); In toluene; at 50 ℃; for 12.5h; under 750.075 Torr; optical yield given as %de; stereoselective reaction; Inert atmosphere;
DOI:10.1002/adsc.201000016