3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane

Base Information

• Chemical Name: 3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane
• CAS No.: 107824-85-1
• Molecular Formula: C₂₈H₃₆GeS
• Molecular Weight: 477.25
• Mol file: 107824-85-1.mol

Synonyms:3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane

Chemical Property of 3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane

There total 1 articles about 3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

hexamesitylcyclotrigermane (107824-84-0) + adamantane-2-thione (23695-65-0) → dispirodithietane-4',2''-adamantane> (31023-85-5) + 3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane (107824-85-1) + C10H14S(Ge(C6H2(CH3)3)2)2 (117308-60-8)

Guidance literature:

In cyclohexane; Irradiation (UV/VIS); photolysis at room temp.; 2.5h; concd.; sepn. by preparative HPLC; elem. anal.;

DOI:10.1021/om00103a020

Reference yield: 50.0%

3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane (107824-85-1) → 3-(2-adamantyl)-4,4-dimesityl-1,2,4-oxathiagermetane S-oxide (117308-61-9)

Guidance literature:

With m-chloroperbenzoic acid; In dichloromethane; under Ar; addn. of 1 equiv. m-chloroperbenzoic acid at 0°C; sepn. by preparative HPLC (mixt. contained 50% unreacted substance); elem. anal.;

DOI:10.1021/om00103a020

Reference yield: 39.0%

3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane (107824-85-1) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → dispirodithietane-4',2''-adamantane> (31023-85-5) + 1,1-bis(2,4,6-trimethylphenyl)-3,4-dimethylgermacyclopent-3-ene (83686-73-1)

Guidance literature:

In cyclohexane; Irradiation (UV/VIS); under Ar; photolysis at room temp.; 5h; sepn. by preparative HPLC;

DOI:10.1021/om00103a020

upstream raw materials:

hexamesitylcyclotrigermane

adamantane-2-thione

Downstream raw materials:

1,1-bis(2,4,6-trimethylphenyl)-3,4-dimethylgermacyclopent-3-ene

adamantane-2-thione

dispirodithietane-4',2''-adamantane>

tetrakis(2,4,6-trimethylphenyl)digermene

Refernces