[Fe(methyl)(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)]

Base Information

• Chemical Name: [Fe(methyl)(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)]
• CAS No.: 415701-49-4
• Molecular Formula: C₃₆H₅₆FeN₂
• Molecular Weight: 572.701
• Mol file: 415701-49-4.mol

Synonyms:[Fe(methyl)(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)]

Chemical Property of [Fe(methyl)(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe(methyl)(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)]

There total 3 articles about [Fe(methyl)(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride (415701-46-1) + methylmagnesium chloride (676-58-4) → [Fe(methyl)(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)] (415701-49-4)

Guidance literature:

In tetrahydrofuran; diethyl ether; (N2); addn. of a soln. of magnesium compd. in THF to a soln. of iron complex in Et2O; evapn., extn. with pentane, filtration through Celite, addn. of hexamethyldisiloxane, cooling to -35°C; elem. anal.;

DOI:10.1021/ja012327l

Reference yield:

[(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl)Fe(μ-H)]2 (647823-71-0) + (2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(methyl) (799267-43-9) → [Fe(methyl)(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)] (415701-49-4)

Guidance literature:

In not given; (N2); thermolysis of a mixt. of iron complexes;

DOI:10.1021/om049415+

Reference yield:

(2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(methyl) (799267-43-9) + (2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl)Fe(isobutyl) (506406-68-4) → [Fe(methyl)(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)] (415701-49-4) + (2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(isobutyl) (506406-65-1)

Guidance literature:

In not given;

DOI:10.1021/om049415+

upstream raw materials:

(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride

methylmagnesium chloride

[(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl)Fe(μ-H)]2

(2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(methyl)

Downstream raw materials:

(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenyl)imidohept-4-yl)Fe(CO)2(COMe)

(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenyl)imidohept-4-yl)Fe(⁽¹³⁾CO)2(⁽¹³⁾COMe)

((((2,6-di(isopropyl)phenyl)N)2C3H-t-Bu2 iron(II)(μ-hydrido))2

(((2,6-di(isopropyl)phenyl)N)2C3H-t-Bu2 iron(II) (diethylether)(η1-BF4)