(S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(phenyl)propanaldehyde dimethyl acetal

Base Information

Chemical Name:(S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(phenyl)propanaldehyde dimethyl acetal
CAS No.:1203466-57-2
Molecular Formula:C₁₈H₂₀O₆S₂
Molecular Weight:396.485
Hs Code.:

Synonyms:(S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(phenyl)propanaldehyde dimethyl acetal

Suppliers and Price of (S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(phenyl)propanaldehyde dimethyl acetal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(phenyl)propanaldehyde dimethyl acetal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(phenyl)propanaldehyde dimethyl acetal

There total 1 articles about (S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(phenyl)propanaldehyde dimethyl acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1222468-58-7
(S)-3-phenyl-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

: 149-73-5
trimethyl orthoformate

: 1203466-57-2
(S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(phenyl)propanaldehyde dimethyl acetal

Guidance literature:: With indium(III) triflate; In dichloromethane; at 20 ℃; for 0.5h; optical yield given as %ee; Inert atmosphere;
DOI:10.1002/chem.200902094

Reference yield: 79.0%

: 1203466-57-2
(S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(phenyl)propanaldehyde dimethyl acetal

: 100-39-0
benzyl bromide

: 1203466-79-8
(S)-3,5-diphenylpentanal dimethyl acetal

Guidance literature:: (S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(phenyl)propanaldehyde dimethyl acetal; benzyl bromide; With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 7h; Inert atmosphere;

With chloro-trimethyl-silane; magnesium; ethylene dibromide; In methanol; at 20 ℃; for 24h; Inert atmosphere;
DOI:10.1002/chem.200902094

Reference yield: 68.0%

: 556-56-9
allyl iodid

: 1203466-57-2
(S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(phenyl)propanaldehyde dimethyl acetal

: 1203466-80-1
(S)-3-phenylhept-6-enal dimethyl acetal

Guidance literature:: allyl iodid; (S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(phenyl)propanaldehyde dimethyl acetal; With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃; Inert atmosphere;

With chloro-trimethyl-silane; magnesium; ethylene dibromide; In methanol; at 20 ℃; for 24h; Inert atmosphere;
DOI:10.1002/chem.200902094