(S)-3-phenyl-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

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Chemical Name:(S)-3-phenyl-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde
CAS No.:1222468-58-7
Molecular Formula:C₁₆H₁₄O₅S₂
Molecular Weight:350.416
Hs Code.:

Synonyms:(S)-3-phenyl-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

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Chemical Property of (S)-3-phenyl-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

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Technology Process of (S)-3-phenyl-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

There total 1 articles about (S)-3-phenyl-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 112520-09-9
2H-benzo[d][1,3]dithiole 1,1,3,3-tetraoxide

: 104-55-2
3-phenyl-propenal

: 1222468-58-7
(S)-3-phenyl-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

Guidance literature:: With (S)-2-(((tert-butyldimethylsilyl)oxy)diphenylmethyl)pyrrolidine; benzoic acid; In tert-butyl methyl ether; at 20 ℃; for 72h; enantioselective reaction;
DOI:10.1016/j.tetlet.2010.01.102

Reference yield: 100.0%

: 1222468-58-7
(S)-3-phenyl-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

: 1203466-56-1
(S)-3-phenyl-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propan-1-ol

Guidance literature:: With sodium tetrahydroborate; In methanol; at 20 ℃; for 0.333333h; enantioselective reaction;
DOI:10.1016/j.tetlet.2010.01.102

Reference yield:

: 1222468-58-7
(S)-3-phenyl-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde

: 18107-18-1
diazomethyl-trimethyl-silane

: 1203466-58-3
(S)-methyl 3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-phenylpropanoate

Guidance literature:: (S)-3-phenyl-3-(1,1,3,3-tetraoxo-2,3-dihydro-1H-1λ(6),3λ(6)-benzo[1,3]dithiol-2-yl)-propionaldehyde; With sodium chlorite; potassium dihydrogenphosphate; dihydrogen peroxide; In methanol; water; acetonitrile; at 0 - 20 ℃;

diazomethyl-trimethyl-silane; In methanol; hexane; toluene; optical yield given as %ee;
DOI:10.1002/chem.200902094