potassium {6-(methoxy)-5-[(methylsulfonyl)amino]-3-pyridinyl}trifluoroborate

Base Information

Chemical Name:potassium {6-(methoxy)-5-[(methylsulfonyl)amino]-3-pyridinyl}trifluoroborate
CAS No.:1361970-56-0
Molecular Formula:C₇H₉BF₃N₂O₃S*K
Molecular Weight:308.131
Hs Code.:

Synonyms:potassium {6-(methoxy)-5-[(methylsulfonyl)amino]-3-pyridinyl}trifluoroborate

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Chemical Property of potassium {6-(methoxy)-5-[(methylsulfonyl)amino]-3-pyridinyl}trifluoroborate

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Technology Process of potassium {6-(methoxy)-5-[(methylsulfonyl)amino]-3-pyridinyl}trifluoroborate

There total 7 articles about potassium {6-(methoxy)-5-[(methylsulfonyl)amino]-3-pyridinyl}trifluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: potassium hydrogen bifluoride

: 1083327-58-5
N-[5-bromo-2-(methyloxy)-3-pyridinyl]methanesulfonamide

: 73183-34-3
bis(pinacol)diborane

: 1361970-56-0
potassium {6-(methoxy)-5-[(methylsulfonyl)amino]-3-pyridinyl}trifluoroborate

Guidance literature:: N-[5-bromo-2-(methyloxy)-3-pyridinyl]methanesulfonamide; bis(pinacol)diborane; With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium acetate; tricyclohexylphosphine; In 1,4-dioxane; at 100 ℃; for 1h;

potassium hydrogen bifluoride; In water; at 20 ℃; for 1h;
DOI:10.1021/acs.oprd.8b00006

Reference yield:

: 67443-38-3
5-bromo-2-chloro-3-nitropyridine

: 1361970-56-0
potassium {6-(methoxy)-5-[(methylsulfonyl)amino]-3-pyridinyl}trifluoroborate

Guidance literature:: Multi-step reaction with 4 steps

1.1: methanol / 2.75 h / 0 - 10 °C / Industry scale; Inert atmosphere

2.1: hydrogenchloride; iron / ethanol; water / 23 h / 10 - 25 °C / Industry scale; Inert atmosphere

3.1: pyridine / acetonitrile / 3 h / 15 - 25 °C / Industry scale; Inert atmosphere

4.1: potassium acetate / tricyclohexylphosphine; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / 1,4-dioxane / 14.5 h / 90 - 100 °C / Inert atmosphere

4.2: 1 h

With pyridine; hydrogenchloride; potassium acetate; iron; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tricyclohexylphosphine; In 1,4-dioxane; methanol; ethanol; water; acetonitrile;

Reference yield:

: 1279123-63-5
potassium hydrogenfluoride

: 1083327-58-5
N-[5-bromo-2-(methyloxy)-3-pyridinyl]methanesulfonamide

: 73183-34-3
bis(pinacol)diborane

: 1361970-56-0
potassium {6-(methoxy)-5-[(methylsulfonyl)amino]-3-pyridinyl}trifluoroborate

Guidance literature:: N-[5-bromo-2-(methyloxy)-3-pyridinyl]methanesulfonamide; bis(pinacol)diborane; With potassium acetate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tricyclohexylphosphine; In 1,4-dioxane; at 90 - 100 ℃; for 14.5h; Inert atmosphere;

potassium hydrogenfluoride; In water; for 1h;