CID 6398716

Base Information

• Chemical Name: CID 6398716
• CAS No.: 14647-25-7
• Molecular Formula: C₂₆H₂₄Cl₂P₂Pt
• Molecular Weight: 664.41
• DSSTox Substance ID: DTXSID50422778
• Mol file: 14647-25-7.mol

Synonyms:NSC276019;14647-25-7;DTXSID50422778

Chemical Property of CID 6398716

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 27.18000
• Density: g/cm³
• LogP: 6.09330
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 665.053475
• Heavy Atom Count: 31
• Complexity: 339

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[PH+](CC[PH+](C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Cl[Pt]Cl

Technology Process of CID 6398716

There total 71 articles about CID 6398716 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → [platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] (83095-83-4,14647-25-7)

Guidance literature:

In dichloromethane; dropwise addn. of 1 equiv. dppe to Pt-complex; crystn. on Et2O addn.;

DOI:10.1016/s0020-1693(97)05688-0

Reference yield: 100.0%

(((C6H5)2PCH2)2)Pt(C4H6O)(CH(Cl)COOC2H5)(1+)*BF4(1-)=[(((C6H5)2PCH2)2)Pt(C4H6O)(CH(Cl)COOC2H5)]BF4 (191790-05-3) + bis(triphenylphosphine)iminium chloride (21050-13-5) → [platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] (83095-83-4,14647-25-7)

Guidance literature:

In dichloromethane; acetonitrile; byproducts: C4H6OCHCOOEt; 80°C (MeCN, 3 h);

Reference yield: 97.0%

hydrogenchloride (7647-01-0,15364-23-5) + Pt(OB(C6H4OMe-4)OB(C6H4OMe-4)O)(dppe) (883153-46-6) → [platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] (83095-83-4,14647-25-7) + 2,4,6-tris(4-methoxyphenyl)boroxine (7294-51-1) + 4-methoxyphenylboronic acid (5720-07-0)

Guidance literature:

In tetrahydrofuran; under N2 or Ar; to a THF soln. of Pt-contg. compd. (0.05 mmol) was addedHCl (0.1 mmol); stirring at room temp. for 2 h; addn. of hexane; the complex was filtered off and dried under vac.; elem. anal.;

DOI:10.1021/om0509903

upstream raw materials:

diacetonitriledichloridopalladium(II)

dichloro(1,5-cyclooctadiene)platinum(ll)

bis(benzonitrile)dichloroplatinum(II)

{(PPhMe2)ClPd(μ-Cl)2PtCl(PPhMe2)}

Downstream raw materials:

(Ph2PCH2CH2PPh2)Pt(η-C2H4)

((C₆H₅)2PCH₂CH₂P(C₆H₅)2)Pt(OCH₃)2

(1,2-bis(diphenylphosphino)ethane)(oxalato)platinum(II)

[PtCl(P(CH₂CH₂CH₂CH₃)3)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)]⁽¹⁺⁾