Biliverdin IX gamma dimethyl ester

Base Information

Chemical Name:Biliverdin IX gamma dimethyl ester
CAS No.:26280-00-2
Deprecated CAS:21494-89-3,58416-08-3
Molecular Formula:C₃₅H₃₈N₄O₆
Molecular Weight:610.71
Hs Code.:

Synonyms:biliverdin IX gamma dimethyl ester

Suppliers and Price of Biliverdin IX gamma dimethyl ester

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Chemical Property of Biliverdin IX gamma dimethyl ester

Chemical Property:

XLogP3:3.2
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:13
Exact Mass:610.27913494
Heavy Atom Count:45
Complexity:1570

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=C(C(=O)NC1=CC2=C(C(=C(N2)C=C3C(=C(C(=CC4=NC(=O)C(=C4C)CCC(=O)OC)N3)C)C=C)C)C=C)CCC(=O)OC
Isomeric SMILES:CC\1=C(C(=O)N/C1=C/C2=C(C(=C(N2)/C=C/3\C(=C(/C(=C/C4=NC(=O)C(=C4C)CCC(=O)OC)/N3)C)C=C)C)C=C)CCC(=O)OC

Technology Process of Biliverdin IX gamma dimethyl ester

There total 21 articles about Biliverdin IX gamma dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4792-10-3
3-{5-Formyl-2-[5-formyl-3-(2-methoxycarbonyl-ethyl)-4-methyl-1H-pyrrol-2-ylmethyl]-4-methyl-1H-pyrrol-3-yl}-propionic acid methyl ester

: 26280-00-2,21494-89-3
biliverdin IX_γ dimethyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: SO₂Cl₂

2: 48 percent / TFA / 2 h / 20 °C

3: pyridine

4: acid / methanol

5: SOCl₂ / dimethylformamide

With thionyl chloride; sulfuryl dichloride; trifluoroacetic acid; In pyridine; methanol; N,N-dimethyl-formamide;
DOI:10.1039/c39810000763

Reference yield:

: 67-56-1
methanol

: 13496-05-4,16009-13-5
iron(III) protoporphyrin IX chloride

: 26280-00-2,21494-89-3
biliverdin IX_γ dimethyl ester

: 26195-58-4
δ-biliverdin-IX dimethyl ester

: 10035-62-8
α-biliverdin-IX dimethyl ester

: β-biliverdin-IX dimethyl ester

Guidance literature:: iron(III) protoporphyrin IX chloride; With ascorbic acid; In pyridine; aq. phosphate buffer; at 37 ℃; for 5h; pH=7;

methanol; With hydrogenchloride; at 4 ℃; for 16h;
DOI:10.1016/j.bbagen.2014.07.021

Reference yield:

: 75630-46-5
benzyl 5-acetoxymethyl-3-(methoxycarbonylmethyl)-4-methylpyrrole-2-carboxylate

: 26280-00-2,21494-89-3
biliverdin IX_γ dimethyl ester

Guidance literature:: Multi-step reaction with 11 steps

1: 81 percent / SnCl₄ / CH₂Cl₂ / 1.5 h / -10 - 0 °C

2: 90 percent / diborane / tetrahydrofuran / 4.5 h

3: 90 percent / pyridine / 2 h / Ambient temperature

4: H₂, Et₃N / 10percent Pd-C / methanol / 20 °C / 760 Torr

5: trifluoroacetic acid / 2 h

6: pyridine / 0.5 h

7: 96 percent / 5percent H₂SO₄ / methanol / 1 h / Heating

8: 72 percent / K₂CO₃, SOCl₂ / CHCl₃; dimethylformamide / 2 h

9: 1.) 10percent KOH, 2.) 14percent BF₃ / 1.) pyridine, methanol, 5 min, 2.) methanol, reflux, 30 min

With potassium hydroxide; thionyl chloride; sulfuric acid; boron trifluoride; hydrogen; tin(IV) chloride; potassium carbonate; triethylamine; trifluoroacetic acid; diborane; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; dichloromethane; chloroform; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)88698-1