Se-4-chlorophenyl benzeneselenoate

Base Information

• Chemical Name: Se-4-chlorophenyl benzeneselenoate
• CAS No.: 94706-41-9
• Molecular Formula: C₁₃H₉ClOSe
• Molecular Weight: 295.627
• Mol file: 94706-41-9.mol

Synonyms:Se-4-chlorophenyl benzeneselenoate

Chemical Property of Se-4-chlorophenyl benzeneselenoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Se-4-chlorophenyl benzeneselenoate

There total 4 articles about Se-4-chlorophenyl benzeneselenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

bis(p-chlorophenyl) diselenide (20541-49-5) + benzoyl chloride (98-88-4) → Se-4-chlorophenyl benzeneselenoate (94706-41-9)

Guidance literature:

With indium; In dichloromethane; for 12h; Inert atmosphere; Reflux;

DOI:10.1016/j.tet.2009.03.069

Reference yield: 86.0%

bis(p-chlorophenyl) diselenide (20541-49-5) + benzoic acid anhydride (93-97-0) → Se-4-chlorophenyl benzeneselenoate (94706-41-9)

Guidance literature:

With C₄₀H₃₂N₄O₇Ti₂⁽²⁺⁾*2C₈F₁₇O₃S^(1-); zinc; In 1,2-dichloro-ethane; at 25 ℃; for 5h;

Reference yield:

1-Chloro-4-iodobenzene (637-87-6) → Se-4-chlorophenyl benzeneselenoate (94706-41-9)

Guidance literature:

Multi-step reaction with 2 steps

1: selenium; copper(II) oxide; potassium hydroxide / dimethyl sulfoxide / 90 °C / Inert atmosphere

2: iron(III) chloride; dibenzoyl peroxide / dichloromethane / 3 h / 20 °C

With iron(III) chloride; selenium; copper(II) oxide; potassium hydroxide; dibenzoyl peroxide; In dichloromethane; dimethyl sulfoxide;

DOI:10.1016/j.tet.2019.130624

upstream raw materials:

bromochlorobenzene

benzoyl chloride

bis(p-chlorophenyl) diselenide

benzoic acid anhydride

Downstream raw materials:

1,3-diphenyl-2-propynone

bis(p-chlorophenyl) diselenide