9-(4-phenylphenyl)carbazole

Base Information

• Chemical Name: 9-(4-phenylphenyl)carbazole
• CAS No.: 6299-16-7
• Molecular Formula: C24H17N
• Molecular Weight: 319.406
• Mol file: 6299-16-7.mol

Synonyms:9-Biphenyl-4-yl-carbazol;9-([1,1'-biphenyl]-4-yl)-9H-carbazole;9-biphenyl-4-yl-carbazole;4-(N-carbazolyl)biphenyl;9-(biphenyl-4-yl)-9H-carbazole;9-(4-biphenylyl)carbazole;9H-Carbazole,9-[1,1'-biphenyl]-4-yl;

Chemical Property of 9-(4-phenylphenyl)carbazole

Chemical Property:

• Vapor Pressure: 1.34E-10mmHg at 25°C
• Melting Point: 224-226℃
• Boiling Point: 512°Cat760mmHg
• Flash Point: 263.5°C
• PSA: 4.93000
• Density: 1.11g/cm³
• LogP: 6.45070
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

9-(4-Biphenylyl)carbazole >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9-(4-phenylphenyl)carbazole

There total 12 articles about 9-(4-phenylphenyl)carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

4-bromo-1,1'-biphenyl (92-66-0) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 9-([1,1’-biphenyl]-4-yl)-9H-carbazole (6299-16-7)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; dicyclohexyl[2-(1-pyrenyl)phenyl]phosphine; sodium t-butanolate; In toluene; at 120 ℃; for 12h; Catalytic behavior; Inert atmosphere; Sealed tube;

Reference yield: 88.75%

4-iodo-biphenyl (1591-31-7) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 9-([1,1’-biphenyl]-4-yl)-9H-carbazole (6299-16-7)

Guidance literature:

With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate; In N,N-dimethyl-formamide; at 153 ℃; Inert atmosphere;

Reference yield: 87.0%

4-bromo-1,1'-biphenyl (92-66-0) + diphenylamine (122-39-4) → 9-([1,1’-biphenyl]-4-yl)-9H-carbazole (6299-16-7)

Guidance literature:

With sodium t-butanolate; 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; In xylene; at 120 ℃; for 7.5h;

upstream raw materials:

4-bromo-1,1'-biphenyl

9H-carbazole

diphenylamine

4-iodo-biphenyl

Downstream raw materials:

9-([1,1'-biphenyl]-3-yl)-9’-([1,1'-biphenyl]-4-yl)-9H,9'H-3,3'-bicarbazole

C₅₃H₃₅N₃

9‐{[1,1'‐biphenyl]‐4‐yl}carbazol‐3‐ylboronic acid

9-([1,1'-biphenyl]-4-yl)-3,6-dibromo-9H-carbazole

Refernces

• 1、 Rowland, Casey A.,Lorzing, Gregory R.,Bhattacharjee, Rameswar,Caratzoulas, Stavros,Yap, Glenn P. A.,Bloch, Eric D.. "Design and synthesis of aryl-functionalized carbazole-based porous coordination cages". supporting information. p. 9352 - 9355. Retrieved 2020/10/02.
• 2、 Xu, Shiyang,Huang, Baoliang,Qiao, Guanyu,Huang, Ziyue,Zhang, Zhen,Li, Zongyang,Wang, Peng,Zhang, Zhenhua. "Rh(III)-Catalyzed C-H Activation of Boronic Acid with Aryl Azide". supporting information. p. 5578 - 5582. Retrieved 2018/09/25.