mer,cis-[TaCl₃(NMe₂)2(NHMe₂)]

Base Information

Chemical Name:mer,cis-[TaCl₃(NMe₂)2(NHMe₂)]
CAS No.:77071-69-3
Molecular Formula:C₆H₁₉Cl₃N₃Ta
Molecular Weight:420.544
Hs Code.:

mer,cis-[TaCl<sub>3</sub>(NMe<sub>2</sub>)2(NHMe<sub>2</sub>)]

Synonyms:mer,cis-[TaCl₃(NMe₂)2(NHMe₂)]

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Chemical Property of mer,cis-[TaCl₃(NMe₂)2(NHMe₂)]

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Technology Process of mer,cis-[TaCl₃(NMe₂)2(NHMe₂)]

There total 1 articles about mer,cis-[TaCl₃(NMe₂)2(NHMe₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 7721-01-9
tantalum pentachloride

: 124-40-3
dimethyl amine

: 77071-69-3
mer,cis-[TaCl₃(NMe₂)2(NHMe₂)]

: 77071-71-7
TaCl₂(N(CH₃)2)3(HN(CH₃)2)

: 77071-70-6
(TaCl₂(N(CH₃)2)2(HN(CH₃)2))2O

: 506-59-2
N,N-dimethylammonium chloride

Guidance literature:: In benzene; dimethylamine added to frozen soln.TaCl5 in benzene at -178°C and slowly allowed to warm to room temp. and soln. stirred for 24 h under N2 atm.; Me2NH2Cl filtered, filtrate concd., pentane added slowly, crystals Ta(NMe2)2Cl3(HNMe2) filtered, filtrate allowed to stand for 10 days - Ta(NMe2)3Cl2(HNMe2) and (TaCl2(NMe2)2(HNMe2))2O; elem. anal.;
DOI:10.1021/ic50220a049

Reference yield: 98.0%

: 77071-69-3
mer,cis-[TaCl₃(NMe₂)2(NHMe₂)]

: 78576-58-6
2,2'-methylene-bis(6-phenylphenol)

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

: 375364-95-7
[TaCl₂(dimethylamido)(dimethylamine)(2,2'-methylenebis(6-phenylphenoxide))]*benzene

Guidance literature:: In benzene; byproducts: (Me2NH2)Cl; under N2, standard Schlenk techniques; benzene soln. of ligand added to soln. of Ta complex in benzene; stirred for 24 h; filtered; supernatant collected; layered with pentane; stood for 24 h; ppt. collected; elem. anal.;
DOI:10.1039/b101723n

Reference yield: 89.0%

: 77071-69-3
mer,cis-[TaCl₃(NMe₂)2(NHMe₂)]

: 577970-30-0,139924-45-1,281213-42-1
(S)-3,3'-bis(methyldiphenylsilyl)-2,2'-dihydroxy-1,1'-dinaphthyl

: 577700-84-6
(S)-[Ta(O₂C₂₀H₁₀(SiMePh₂)2-3,3')(NHMe₂)(NMe₂)Cl₂]

Guidance literature:: In benzene; byproducts: [Me2NH2][Cl]; in Schlenk line; a soln. of a ligand in benzene was slowly added with stirring to a soln. of Ta-contg. compd. in benzene; the mixt. was stirred for 1 h; the mixt. was evapd. to dryness; the solid was dissolved in a small amt.of benzene and filtered; the supernatant was reduced in vol. and layere d with pentane-hexane; elem. anal.;
DOI:10.1039/b212910h