C₁₅H₂₁ClO₂SSi

Base Information

• Chemical Name: C₁₅H₂₁ClO₂SSi
• CAS No.: 1189373-68-9
• Molecular Formula: C₁₅H₂₁ClO₂SSi
• Molecular Weight: 328.935
• Mol file: 1189373-68-9.mol

Synonyms:C₁₅H₂₁ClO₂SSi

Chemical Property of C₁₅H₂₁ClO₂SSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of C₁₅H₂₁ClO₂SSi

There total 1 articles about C₁₅H₂₁ClO₂SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro-trimethyl-silane (75-77-4) + C12H13ClO2S (1190220-11-1) → C15H21ClO2SSi (1189373-68-9)

Guidance literature:

C₁₂H₁₃ClO₂S; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1h;

chloro-trimethyl-silane; at -78 - 20 ℃; for 14h;

DOI:10.1016/j.tet.2009.06.119

Reference yield: 55.0%

C15H21ClO2SSi (1189373-68-9) + dimethyl acetylenedicarboxylate (762-42-5) → dimethyl 3-hydroxy-6-(4-chlorophenylsulfanyl)-4-methylphthalate (1189373-89-4)

Guidance literature:

C₁₅H₂₁ClO₂SSi; dimethyl acetylenedicarboxylate; at -78 - 20 ℃; for 20h; Inert atmosphere; neat (no solvent);

With ammonium chloride; In water; Inert atmosphere;

DOI:10.1055/s-0029-1216828

Reference yield: 55.0%

C15H21ClO2SSi (1189373-68-9) + dimethyl penta-2,3-dienedioate (1712-36-3) → methyl 4-[(4-chlorophenyl)sulfanyl]-6-hydroxy-2-(2-methoxy-2-oxoethyl)-3-methylbenzoate (1229787-61-4)

Guidance literature:

C₁₅H₂₁ClO₂SSi; dimethyl penta-2,3-dienedioate; at 50 - 70 ℃; for 12h;

With triethylamine hydrofluoride; In ethanol; at 20 ℃; for 0.166667h; regioselective reaction;

DOI:10.1002/hlca.200900348

upstream raw materials:

chloro-trimethyl-silane

C₁₂H₁₃ClO₂S

Downstream raw materials:

2-(4-chlorophenylsulfanyl)-3,4,6-trimethyl-benzoic acid methyl ester

dimethyl 3-hydroxy-6-(4-chlorophenylsulfanyl)-4-methylphthalate

methyl 4-[(4-chlorophenyl)sulfanyl]-6-hydroxy-2-(2-methoxy-2-oxoethyl)-3-methylbenzoate

methyl 2-[(4-chlorophenyl)sulfanyl]-3,4,6-trimethyl-5-(phenylselanyl)benzoate