1,3,3-trimethyl-2-[(phenylazo)methylene]indoline

Base Information

• Chemical Name: 1,3,3-trimethyl-2-[(phenylazo)methylene]indoline
• CAS No.: 4677-09-2
• Molecular Formula: C18H19N3
• Molecular Weight: 277.369
• European Community (EC) Number: 225-130-7
• ChEMBL ID: CHEMBL1199390
• DSSTox Substance ID: DTXSID7063554
• Nikkaji Number: J28.043G
• Mol file: 4677-09-2.mol

Synonyms:1,3,3-Trimethyl-2-phenylazomethylen-indolin;

Chemical Property of 1,3,3-trimethyl-2-[(phenylazo)methylene]indoline

Chemical Property:

• Vapor Pressure: 6.88E-06mmHg at 25°C
• Boiling Point: 377.2°C at 760 mmHg
• Flash Point: 181.9°C
• PSA: 27.96000
• Density: 1.06g/cm³
• LogP: 5.10430
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 277.157897619
• Heavy Atom Count: 21
• Complexity: 418

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(C2=CC=CC=C2N(C1=CN=NC3=CC=CC=C3)C)C
• Isomeric SMILES: CC\1(C2=CC=CC=C2N(/C1=C\N=NC3=CC=CC=C3)C)C

Technology Process of 1,3,3-trimethyl-2-[(phenylazo)methylene]indoline

There total 7 articles about 1,3,3-trimethyl-2-[(phenylazo)methylene]indoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzene diazonium chloride (100-34-5) → 1,3,3-trimethyl-2-phenylazomethylene-indoline (4677-09-2)

Guidance literature:

With sodium hydroxide; at 0 ℃;

Reference yield:

2,3,3-trimethylindoleniune (1640-39-7) + benzene diazonium chloride (100-34-5) + methyl iodide (74-88-4) → 1,3,3-trimethyl-2-phenylazomethylene-indoline (4677-09-2)

Guidance literature:

With acetic acid; Behandeln des erhaltenen Jodids mit wss. NH₃;

Reference yield:

1,2,3,3-tetramethyl-3H-indolium iodide (5418-63-3) + phenylhydrazine (100-63-0) → 1,3,3-trimethyl-2-phenylazomethylene-indoline (4677-09-2)

Guidance literature:

at 120 ℃;

upstream raw materials:

2,3,3-trimethylindoleniune

benzene diazonium chloride

methyl iodide

benzenediazonium

Downstream raw materials:

2-(phenylazomethylene)-1,3,3-trimethylindoline perchlorate