iron(III) phosphate

Base Information

• Chemical Name: iron(III) phosphate
• CAS No.: 765207-04-3
• Molecular Formula: Fe*O₄P
• Molecular Weight: 150.818
• Mol file: 765207-04-3.mol

Synonyms:iron(III) phosphate

Chemical Property of iron(III) phosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of iron(III) phosphate

There total 7 articles about iron(III) phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ammonium dihydrogen phosphate (7722-76-1,10124-31-9,10361-65-6,7783-28-0) + Ammonium iron sulfate → ferric pyrophosphate (10058-44-3) + iron(III) phosphate (765207-04-3)

Guidance literature:

With H₂O₂; In ethanol; water; soln. of Fe(NH4)2(SO4)2*6H2O (pH 4.9) added at ambient temp. to stirred soln. of (NH4)H2PO4 in water-EtOH (1.5:1, v/v) in 1:1 vol. proportion; concd. soln. of H2O2 added; ppt. kept in contact with mother liquor for 30 min without stirring; ppt. collected on membrane filter; washed (H2O); dried at room temp. in air for 2 ds; calcined in air at 750°C for 10 h; monitored by X-ray diffraction;

DOI:10.1016/j.tca.2003.10.024

Reference yield:

(C2H10N2)(2+)*3Fe(2+)*4HPO3(2-)=(C2H10N2)[Fe3(HPO3)4] → ferric pyrophosphate (10058-44-3) + iron(III) phosphate (765207-04-3) + iron(III) phosphate (765207-04-3)

Guidance literature:

In neat (no solvent, solid phase); heating from room temp. up to 815°C; detd. by time-resolved X-ray thermal diffractometry in air;

DOI:10.1016/j.jssc.2004.04.020

Reference yield:

(C2H10N2)(2+)*3Fe(2+)*4HPO3(2-)=(C2H10N2)[Fe3(HPO3)4] → ferric pyrophosphate (10058-44-3) + iron(III) phosphate (765207-04-3) + iron(III) phosphate (765207-04-3)

Guidance literature:

In neat (no solvent, solid phase); heating from room temp. up to 815°C; detd. by time-resolved X-ray thermal diffractometry in air;

DOI:10.1016/j.jssc.2004.04.020

upstream raw materials:

ammonium dihydrogen phosphate

phosphorus

chlorine

Downstream raw materials:

hydrogenchloride

sodium dihydrogenphosphate

iron(II) oxide

iron(III) chloride

Refernces

• 1、 Schoeneborn,Glaum. "Crystal growth, single-crystal structure refinement and unusual ligand-field splittings of lazulite-type oxidephosphates MTi2O 2(PO4)I (M = FeII, CoII, Ni II)". . p. 2568 - 2578. Retrieved 2007.
• 2、 Chung, U-Chan,Mesa, Jose L.,Pizarro, Jose L.,Lezama, Luis,Garitaonandia, Jose S.,Chapman, Jon P.,Arriortua, Maria I.. "A new layered organically templated iron(II) phosphite, (C 2H10N2)[Fe3(HPO3) 4]. Hydrothermal synthesis, crystal structure and spectroscopic and magnetic properties". . p. 2705 - 2713. Retrieved 2008/10/09.