Platinum oxide

Base Information

• Chemical Name: Platinum oxide
• CAS No.: 11129-89-8
• Molecular Formula: O2Pt
• Molecular Weight: 226.95
• European Community (EC) Number: 234-831-7
• NSC Number: 128165
• DSSTox Substance ID: DTXSID1065188
• Wikidata: Q1676613
• Mol file: 11129-89-8.mol

Synonyms:platinum oxide;PtO2

Chemical Property of Platinum oxide

Chemical Property:

• Melting Point: 450℃
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 210.959709
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): R38:; R41:; R8:
• Hazard Codes: O:Oxidizing agent
• Statements: R38:; R41:; R8:
• Safety Statements: S17:; S22:; S26:; S28A:; S36/37/39:

MSDS Files:

Useful:

• Canonical SMILES: O=[Pt]

Technology Process of Platinum oxide

There total 54 articles about Platinum oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

platinum tetrammine hydroxide → platinum(II) oxide (11129-89-8) + nitrogen (7727-37-9) + ammonia (7664-41-7) + water (7732-18-5) + dinitrogen monoxide (10024-97-2)

Guidance literature:

With O₂; In neat (no solvent, solid phase); Pt-complex is supported on SiO2, heating up to 500 °C, 10% He, 10% O2, 80% Ar gas flow;

DOI:10.1016/S0021-9517(03)00189-1

Reference yield:

platinum (7440-06-4) → platinum(IV) oxide (1314-15-4) + platinum(II) oxide (11129-89-8)

Guidance literature:

With O₂; High Pressure; at 350°C, treating with aqua regia; washing with alcohol-benzene mixt., drying at 130-140°C;

Reference yield:

oxygen (80937-33-3) + platinum (7440-06-4) → platinum(IV) oxide (1314-15-4) + platinum(II) oxide (11129-89-8)

Guidance literature:

at 510 °C; mixt of 70% PtO and 30% PtO2;

upstream raw materials:

cisplatin

oxygen

platinum

platinum(II) chloride

Refernces

• 1、 Rani, Soni,Kumar, Sumit,Chandra, Sulekh. "Synthesis of NNNN tetradentate macrocyclic ligand and its Pd(II), Pt(II), Ru(III), and Ir(III) complexes: Spectroscopic, Thermal, and antimicrobial studies". . p. 940 - 946. Retrieved 2010.
• 2、 Pal, Biswajit,Gupta, Kalyan K. Sen. "Kinetics and mechanism of the inner-sphere reduction of hexachloroplatinate(IV) by dithionite in acetate buffer". . p. 671 - 678. Retrieved 2012.
• 3、 Naito, Shuichi,Tanimoto, Mitsutoshi. "". . p. 300 - 310. Retrieved 1989.
• 4、 Li, Qinglin,Chen, Zhengshi,Zheng, Xinhua,Jin, Zhensheng. "Study of Photoreduction of PtCl62- on CdS". . p. 5959 - 5962. Retrieved 1992.
• 5、 Bakr, Eman A.,Al-Hefnawy, Gad B.,Awad, Mohamed K.,Abd-Elatty, Hossam H.,Youssef, Mohamed S.. "New Ni(II), Pd(II) and Pt(II) complexes coordinated to azo pyrazolone ligand with a potent anti-tumor activity: Synthesis, characterization, DFT and DNA cleavage studies". . . Retrieved 2018.
• 6、 Atlam, Faten M.,El-Nahass, Marwa N.,Bakr, Eman A.,Fayed, Tarek A.. "Metal complexes of chalcone analogue: Synthesis, characterization, DNA binding, molecular docking and antimicrobial evaluation". . . Retrieved 2018.