{(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾

Base Information

Chemical Name:{(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾
CAS No.:35797-14-9
Molecular Formula:C₁₃H₉CrNO₅
Molecular Weight:311.214
Hs Code.:

{(N-methylamino)phenylcarbene}pentacarbonylchromium<sup>(0)</sup>

Synonyms:{(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾

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Chemical Property of {(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾

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Technology Process of {(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾

There total 2 articles about {(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 26160-57-6
pentacarbonyl(ethoxyphenylmethylene)chromium⁽⁰⁾

: 74-89-5
methylamine

: 35797-14-9
{(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾

Guidance literature:: In diethyl ether; a soln. of complex in diethyl ether was treated with methylamine at roomtemp. under Ar until the color changed from red to yellow; the mixt. was diluted with H2O, extd. with CH2Cl2, dried over Na2SO4, concd., flash chromy. with CH2Cl2-petroleum ether; elem. anal.;
DOI:10.1016/S0022-328X(00)00728-2

Reference yield: 80.0%

: 306-37-6
N,N'-Dimethylhydrazine dihydrochloride

: 27436-93-7
pentacarbonyl(1-methoxybenzylidene)chromium⁽⁰⁾

: 35797-14-9
{(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾

: (CO)5CrC(C₆H₅)N(CH₃)NHCH₃

Guidance literature:: With n-butyllithium; lithium chloride; In tetrahydrofuran; (N2); react. of hydrochloride with BuLi at 0°C, react. with complex and LiCl at -78 to -20°C for 15 h;
DOI:10.1039/a900166b

Reference yield: 84.0%

: 35797-14-9
{(N-methylamino)phenylcarbene}pentacarbonylchromium⁽⁰⁾

: 100-39-0
benzyl bromide

: (CO)5CrCN(CH₃)(CH₂C₆H₅)C₆H₅

Guidance literature:: With NaOH; tetrabutylammonium bromide; In benzene; the soln. of complex and tetrabutylammonium bromide in benzene was treated with 50% aq. NaOH and benzyl bromide, stirred at room temp. under Ar for 2 h; the mixt. was diluted with H2O, extd. with CH2Cl2, dried over Na2SO4, concd., flash chromy.; elem. anal.;
DOI:10.1016/S0022-328X(00)00728-2