TMSOC₆H₅MeOMe

Base Information

Chemical Name:TMSOC₆H₅MeOMe
CAS No.:219646-62-5
Molecular Formula:C₁₁H₂₀O₂Si
Molecular Weight:212.364
Hs Code.:

Synonyms:TMSOC₆H₅MeOMe

Suppliers and Price of TMSOC₆H₅MeOMe

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of TMSOC₆H₅MeOMe

Chemical Property:

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Safty Information:

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Technology Process of TMSOC₆H₅MeOMe

There total 1 articles about TMSOC₆H₅MeOMe which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 25112-91-8
3-methoxy-2-methylcyclohex-2-en-1-one

: 219646-62-5
TMSOC₆H₅MeOMe

Guidance literature:: 3-methoxy-2-methylcyclohex-2-en-1-one; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 0.166667h;

chloro-trimethyl-silane; In tetrahydrofuran; at -78 ℃; for 1h; Further stages.;
DOI:10.1021/ja7113486

Reference yield:

: 219646-62-5
TMSOC₆H₅MeOMe

: 1523187-51-0
C₃₆H₄₂O₆Si

Guidance literature:: Multi-step reaction with 4 steps

1.1: 5,5-dimethyl-1,3-cyclohexadiene / 2 h / -10 °C

1.2: 2 h / 120 °C

2.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 16 h / 20 °C

3.1: potassium hydroxide; methanol / 5 h / Reflux

4.1: acetic anhydride / 3 h / 105 °C

With methanol; di-isopropyl azodicarboxylate; acetic anhydride; triphenylphosphine; potassium hydroxide; In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene;
DOI:10.1055/s-0033-1340060

Reference yield:

: 219646-62-5
TMSOC₆H₅MeOMe

: 1523187-59-8
(E)-3-hydroxy-5-{[7-isothiocyanato-3,7-dimethyl-6-(phenylselanyl)oct-2-en-1-yl]oxy}-7-methoxy-3,6-dimethylisobenzofuran-1(3H)-one

Guidance literature:: Multi-step reaction with 6 steps

1.1: 5,5-dimethyl-1,3-cyclohexadiene / 2 h / -10 °C

1.2: 2 h / 120 °C

2.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 13 h / 20 °C

3.1: potassium hydroxide; methanol / 5 h / Reflux

4.1: acetic anhydride / 3 h / 105 °C

5.1: cadmium(II) chloride / diethyl ether / 1 h / Inert atmosphere; Reflux

5.2: 4 h / Inert atmosphere; Reflux

6.1: [bis(acetoxy)iodo]benzene / acetonitrile / 16 h / 20 °C

With methanol; [bis(acetoxy)iodo]benzene; di-isopropyl azodicarboxylate; acetic anhydride; triphenylphosphine; potassium hydroxide; cadmium(II) chloride; In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene; diethyl ether; acetonitrile;
DOI:10.1055/s-0033-1340060