Technology Process of TMSOC6H5MeOMe
There total 1 articles about TMSOC6H5MeOMe which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
3-methoxy-2-methylcyclohex-2-en-1-one;
With
lithium diisopropyl amide;
In
tetrahydrofuran;
at -78 ℃;
for 0.166667h;
chloro-trimethyl-silane;
In
tetrahydrofuran;
at -78 ℃;
for 1h;
Further stages.;
DOI:10.1021/ja7113486
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: 5,5-dimethyl-1,3-cyclohexadiene / 2 h / -10 °C
1.2: 2 h / 120 °C
2.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 16 h / 20 °C
3.1: potassium hydroxide; methanol / 5 h / Reflux
4.1: acetic anhydride / 3 h / 105 °C
With
methanol; di-isopropyl azodicarboxylate; acetic anhydride; triphenylphosphine; potassium hydroxide;
In
tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene;
DOI:10.1055/s-0033-1340060
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: 5,5-dimethyl-1,3-cyclohexadiene / 2 h / -10 °C
1.2: 2 h / 120 °C
2.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 13 h / 20 °C
3.1: potassium hydroxide; methanol / 5 h / Reflux
4.1: acetic anhydride / 3 h / 105 °C
5.1: cadmium(II) chloride / diethyl ether / 1 h / Inert atmosphere; Reflux
5.2: 4 h / Inert atmosphere; Reflux
6.1: [bis(acetoxy)iodo]benzene / acetonitrile / 16 h / 20 °C
With
methanol; [bis(acetoxy)iodo]benzene; di-isopropyl azodicarboxylate; acetic anhydride; triphenylphosphine; potassium hydroxide; cadmium(II) chloride;
In
tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene; diethyl ether; acetonitrile;
DOI:10.1055/s-0033-1340060
