(+)589-dichloro((RR)-o-phenylenebis(methylphenylphosphine))platinum(II)

Base Information

Chemical Name:(+)589-dichloro((RR)-o-phenylenebis(methylphenylphosphine))platinum(II)
CAS No.:77029-52-8
Molecular Formula:C₂₀H₂₀Cl₂P₂Pt
Molecular Weight:588.312
Hs Code.:

Synonyms:(+)589-dichloro((RR)-o-phenylenebis(methylphenylphosphine))platinum(II)

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Chemical Property of (+)589-dichloro((RR)-o-phenylenebis(methylphenylphosphine))platinum(II)

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Technology Process of (+)589-dichloro((RR)-o-phenylenebis(methylphenylphosphine))platinum(II)

There total 1 articles about (+)589-dichloro((RR)-o-phenylenebis(methylphenylphosphine))platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 12080-32-9
dichloro(1,5-cyclooctadiene)platinum(ll)

: 72091-01-1,72091-02-2,72150-36-8,72150-63-1,77410-05-0
(S,S)-1,2-bis(methylphenylphosphino)benzene

: 77029-52-8
(+)589-dichloro((RR)-o-phenylenebis(methylphenylphosphine))platinum(II)

Guidance literature:: With hydrogenchloride; sodium carbonate; In methanol; suspn. (PtCl2(1,5-C8H12)) and Na2CO3 heated in methanol for 15 min, soln. filtered and reacted with (SS)-diphos, hydrochloric acid added;

Reference yield: 99.0%

: 52120-04-4,55289-90-2,55289-91-3,57341-01-2,57375-33-4
meso-o-phenylenebis(methylphenylarsine)

: 77029-52-8
(+)589-dichloro((RR)-o-phenylenebis(methylphenylphosphine))platinum(II)

: 67-64-1
acetone

: 77060-02-7
(+)589-chloro((RS)-o-phenylenebis(methylphenylarsine))((SS)-o-phenylenebis(methylphenylphosphine))platinum(II) chloride acetone hemisolvate

Guidance literature:: In hexane; dichloromethane; acetone; (PdCl2(SS)-diphos)) in dichloromethane treated with soln. (RS)-diars indichloromethane, soln. filtered and evapd. to dryness, product recrystd. from acetone-hexane; elem. anal.;

Reference yield: 84.0%

: ammonium hexafluorophosphate

: 77029-52-8
(+)589-dichloro((RR)-o-phenylenebis(methylphenylphosphine))platinum(II)

: 6372-48-1
methylphenylphosphine

: 145554-97-8,145519-45-5
SP-4-2-[(S,S),(S,R)]-chloro(methylphenylphosphine)[1,2-phenylenebis(methylphenylphosphine)]platinum(II) hexafluorophosphate

Guidance literature:: With CF₃SO₃H; In water; acetone; Ar-atmosphere; stirring equimolar amts. of Pt-complex (in Me2CO) with AgNO3 (in H2O) for 1 h (absence of light), filtration off of AgCl, washing (hot Me2CO), treatment of filtrate with CF3SO3H, 2 equivs. of NH4PF6 and 1 equiv. of phosphine; solvent removal, dissoln. in CH2Cl2, addn. of H2O, drying of org. layer(MgSO4), partial evapn., pptn. on Et2O addn., fractional crystn. (CH2Cl2/Et2O), filtration, washing (CH2Cl2/Et2O=100:65), drying; elem. anal.;