1-(Tetradecanoyloxy)propan-2-yl pentadecanoate

Base Information

• Chemical Name: 1-(Tetradecanoyloxy)propan-2-yl pentadecanoate
• CAS No.: 107-98-2
• Molecular Formula: C4H10O2
• Molecular Weight: 90.1222
• Hs Code.: 29094919
• Metabolomics Workbench ID: 75621
• Mol file: 107-98-2.mol

Synonyms:1-(tetradecanoyloxy)propan-2-yl pentadecanoate;LS-2522;1-tetradecanoyloxypropan-2-yl pentadecanoate;LMFA07011007

Chemical Property of 1-(Tetradecanoyloxy)propan-2-yl pentadecanoate

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: 10.9 mm Hg ( 25 °C)
• Melting Point: - 97 °C
• Refractive Index: n20/D 1.403(lit.)
• Boiling Point: 118.5 °C at 760 mmHg
• PKA: 14.49±0.20(Predicted)
• Flash Point: 33.9 °C
• PSA: 29.46000
• Density: 0.912 g/cm³
• LogP: 0.01360
• Storage Temp.: Store at +2°C to +25°C.
• Sensitive.: Hygroscopic
• Solubility.: water: miscible
• Water Solubility.: soluble
• XLogP3: 13.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 30
• Exact Mass: 510.46481045
• Heavy Atom Count: 36
• Complexity: 477

Purity/Quality:

99% ^*data from raw suppliers

PMEL ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R10:
• Hazard Codes: T
• Statements: 10-67-61
• Safety Statements: 24-26-24/25-45-53

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCCCCCCCCCCCC(=O)OC(C)COC(=O)CCCCCCCCCCCCC
• Uses: 1-Methoxy-2-propanol is primarily used in the manufacture of lacquers and paints, as an anti-freeze in industrial engines, a tailing agent for inks used on very high-speed presses, a coupling agent for resins and dyes in waterbased inks, and a solvent for celluloses, acrylics, dyes, inks, and stains. It is also used in cleaning products such as glass and rug cleaners, carbon and grease removers, and paint and varnish removers; and in pesticide formulations as a solvent for applications to crops and animals. 1-Methoxy-2-propanol is used as a solvent for cellulose, acrylics, dyes, inks, and cellophane. 1-Methoxy-2-propanol acts as a good biological indicator. 1-Methoxy-2-propanol is mainly used as solvent, dispersant and diluent, as well as fuel antifreeze, extractant, etc. Used as solvent of nitrocellulose, compounding agent of brake oil and detergent, etc. Widely used in coatings and cleaners. It can be used as the active solvent of water-based coatings; Active solvent and coupling agent of solvent based printing ink; Solvent for ballpoint pens and pens; Coupling agents and solvents for household and industrial cleaners, derusting agents and hard surface cleaners; Solvents for agricultural pesticides; Mixed with propylene glycol n-butyl ether for glass cleaner formula. A glycol ether and a good biological indicator of exposure.

Technology Process of 1-(Tetradecanoyloxy)propan-2-yl pentadecanoate

There total 49 articles about 1-(Tetradecanoyloxy)propan-2-yl pentadecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → 1-methoxy-2-propanol (107-98-2) + methyloxirane (75-56-9,16033-71-9)

Guidance literature:

With pyridine N-oxide; dihydrogen peroxide; methyltrioxorhenium(VII); In methanol; water; at 40 ℃; for 3h; under 11894.7 - 36201.3 Torr;

Reference yield: 92.0%

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → propylene glycol (57-55-6,63625-56-9) + 1-methoxy-2-propanol (107-98-2) + 2-methoxypropanol (1589-47-5) + methyloxirane (75-56-9,16033-71-9)

Guidance literature:

With dihydrogen peroxide; titanium-silicate; In methanol; at 40 ℃;

Reference yield: 72.73%

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → propylene glycol (57-55-6,63625-56-9) + 1-methoxy-2-propanol (107-98-2) + methyloxirane (75-56-9,16033-71-9)

Guidance literature:

With pyridine N-oxide; dihydrogen peroxide; methyltrioxorhenium(VII); In methanol; water; at 40 ℃; for 3h; under 36201.3 Torr;

upstream raw materials:

Methoxyacetone

methanol

methyloxirane

sodium methylate

Downstream raw materials:

Methoxyacetone

propylene glycol methyl ether acetate

(+/-)-(methoxyprop-2-yl) methanesulphonate

(S)-1-methoxypropan-2-yl 4-methylbenzenesulfonate

Refernces

• 1、 Olah,G.A.,Sommer,J.. "-". . p. 4323 - 4327. Retrieved 1968.
• 2、 Bai, Yu,Cai, Qinghai,Wang, Xiaoguang,Lu, Bin. "Tunable synthesis of propylene glycol ether from methanol and propylene oxide under ambient pressure". . p. 386 - 390. Retrieved 2011.
• 3、 Prieto, Alejandro,Palomino, Miguel,Díaz, Urbano,Corma, Avelino. "One-pot two-step process for direct propylene oxide production catalyzed by bi-functional Pd(Au)@TS-1 materials". . p. 73 - 84. Retrieved 2016.
• 4、 Li, Yi-Chuan,Shen, Ben-Xian,Zhao, Ji-Gang. "Effect of propylene glycol monomethyl ether and rust impurities on TS-1 deactivation in propylene epoxidation". . p. 169 - 174. Retrieved 2013.
• 5、 Chatterjee, Abhijit,Chatterjee, Maya,Kawanami, Hajime,Kitta, Mitsunori. "Selectivity controlled transformation of carbon dioxide into a versatile bi-functional multi-carbon oxygenate using a physically mixed ruthenium-iridium catalyst". . p. 4719 - 4731. Retrieved 2021.
• 6、 Liu, Ning,Wu, Zhimin,Li, Meng,Li, Shanshan,Li, Yongfei,Yu, Rongdong,Pan, Langsheng,Liu, Yuejin. "A novel strategy for constructing mesoporous solid superbase catalysts: Bimetallic Al-La oxides supported on SBA-15 modified with KF". . p. 725 - 733. Retrieved 2017.
• 7、 Wang, Lina,Wang, Yaquan,Wu, Guoqiang,Feng, Wenping,Zhang, Teng,Yang, Rumin,Jin, Xing,Shi, Hainan,Wang, Shuhai. "Epoxidation of propylene over titanosilicate-1 in fixed-bed reactor: Experiments and kinetics". . p. 943 - 950. Retrieved 2014.
• 8、 Zuo, Yi,Liu, Min,Zhang, Ting,Meng, Changgong,Guo, Xinwen,Song, Chunshan. "Enhanced Catalytic Performance of Titanium Silicalite-1 in Tuning the Crystal Size in the Range 1200-200nm in a Tetrapropylammonium Bromide System". . p. 2660 - 2668. Retrieved 2015.
• 9、 Liang, Shuguang,Liu, Huizhen,Zhou, Yinxi,Jiang, Tao,Han, Buxing. "The tetramethylguanidine-based ionic liquid-catalyzed synthesis of propylene glycol methyl ether". . p. 2534 - 2536. Retrieved 2010.
• 10、 Ingleson, Michael J.,Barrio, Jorge Perez,Bacsa, John,Dickinson, Calum,Park, Hyunsoo,Rosseinsky, Matthew J.. "Generation of a solid Bronsted acid site in a chiral framework". . p. 1287 - 1289. Retrieved 2008.