cyclohexyl cyclohexanesulfinate

Base Information

• Chemical Name: cyclohexyl cyclohexanesulfinate
• CAS No.: 135469-43-1
• Molecular Formula: C₁₂H₂₂O₂S
• Molecular Weight: 230.371
• Mol file: 135469-43-1.mol

Synonyms:cyclohexyl cyclohexanesulfinate

Chemical Property of cyclohexyl cyclohexanesulfinate

Chemical Property:

Purity/Quality:

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Technology Process of cyclohexyl cyclohexanesulfinate

There total 3 articles about cyclohexyl cyclohexanesulfinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

cyclohexyl trifluoromethanesulfinate + cyclohexylmagnesiumchloride (931-51-1) → cyclohexyl cyclohexanesulfinate (135469-43-1)

Guidance literature:

In diethyl ether; toluene; at 20 ℃; for 1.08333h; Cooling with ice;

DOI:10.1016/j.jfluchem.2013.03.020

Reference yield:

cyclohexane (110-82-7,25012-93-5) → cyclohexylcyclohexane (92-51-3) + dicyclohexyl sulfone (28797-07-1) + S-cyclohexyl cyclohexane-1-sulfonothioate (4837-39-2) + cyclohexanesulfonic acid (6922-46-9) + cyclohexanesulfinic acid (5675-01-4) + cyclohexyl cyclohexanesulfinate (135469-43-1)

Guidance literature:

With sulfur dioxide; hydrogen; mercury; at 30 ℃; for 1.75h; Mechanism; Product distribution; Irradiation; other alkanes and alkenes; other reaction conditions, also without H₂;

DOI:10.1021/jo00019a006

Reference yield:

cyclohexanol (108-93-0) → cyclohexyl cyclohexanesulfinate (135469-43-1)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 2-mesitylenesulphonyl chloride / acetonitrile / 1 h / 20 °C

1.2: 18 h / 20 °C / Cooling with ice

2.1: diethyl ether; toluene / 1.08 h / 20 °C / Cooling with ice

With 2-mesitylenesulphonyl chloride; In diethyl ether; toluene; acetonitrile;

DOI:10.1016/j.jfluchem.2013.03.020

upstream raw materials:

cyclohexane

cyclohexylmagnesiumchloride

cyclohexanol