Bis(p-nitrophenyl) sulfoxide

Base Information

• Chemical Name: Bis(p-nitrophenyl) sulfoxide
• CAS No.: 1774-38-5
• Molecular Formula: C12H8 N2 O5 S
• Molecular Weight: 292.272
• Hs Code.: 2930909090
• NSC Number: 154268,82906
• DSSTox Substance ID: DTXSID60170298
• Nikkaji Number: J1.278.770G
• Wikidata: Q83040210
• Mol file: 1774-38-5.mol

Synonyms:1774-38-5;Bis(p-nitrophenyl) sulfoxide;1-nitro-4-(4-nitrophenyl)sulfinylbenzene;Bis(4-nitrophenyl) sulfoxide;4,4'-Dinitrodiphenyl sulfoxide;Benzene, 1,1'-sulfinylbis(4-nitro-;BIS-(4-NITRO-PHENYL)SULFOXIDE;Sulfoxide, bis(p-nitrophenyl);1,1'-Sulfinylbis(4-nitrobenzene);NSC 82906;NSC 154268;BIS-(4-NITRO-PHENYL) SULFOXIDE;BRN 1999385;Benzene, 1,1'-sulfinylbis[4-nitro-;Benzene, 1,1'-sulfinylbis(4-nitro- (9CI);p-nitrophenyl sulfoxide;Bis[p-nitrophenyl]sulfoxide;di(4-nitrophenyl) sulfoxide;NCIOpen2_004692;SCHEMBL1576857;DTXSID60170298;NSC82906;NSC-82906;NSC154268;AKOS003235543;NSC-154268;LS-148122;1-Nitro-4-[(4-nitrophenyl)sulfinyl]benzene #;1-NITRO-4-(4-NITROBENZENESULFINYL)BENZENE

Chemical Property of Bis(p-nitrophenyl) sulfoxide

Chemical Property:

• Vapor Pressure: 1.7E-10mmHg at 25°C
• Melting Point: 160 °C (decomp)(Solv: benzene (71-43-2))
• Boiling Point: 522.6°Cat760mmHg
• Flash Point: 269.8°C
• PSA: 127.92000
• Density: 1.58g/cm³
• LogP: 4.58180
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 2
• Exact Mass: 292.01539253
• Heavy Atom Count: 20
• Complexity: 354

Purity/Quality:

99% ^*data from raw suppliers

1,1'-SULFINYLBIS(4-NITROBENZENE) 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1[N+](=O)[O-])S(=O)C2=CC=C(C=C2)[N+](=O)[O-]

Technology Process of Bis(p-nitrophenyl) sulfoxide

There total 12 articles about Bis(p-nitrophenyl) sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

bis(4-nitrophenyl)sulfide (1223-31-0) → 4,4'-dinitrodiphenyl sulfoxide (1774-38-5)

Guidance literature:

With dipotassium peroxodisulfate; In acetic acid; at 60 ℃; for 5h;

Reference yield: 10.0%

bis(4-nitrophenyl)sulfide (1223-31-0) → 4,4'-dinitrodiphenyl sulfoxide (1774-38-5) + 4-nitrophenyl sulfone (1156-50-9)

Guidance literature:

With dihydrogen peroxide; methyltrioxorhenium(VII); In ethanol; at 50 ℃; for 5h;

DOI:10.1246/bcsj.69.2955

Reference yield:

diphenyl sulfide (139-66-2) + nitric acid (7697-37-2,78989-43-2) → 4,4'-dinitrodiphenyl sulfoxide (1774-38-5) + 3,3'-dinitrodiphenyl sulfone (1228-53-1) + 2,2'-dinitrophenyl sulphoxide (30388-70-6)

Guidance literature:

at 25 ℃;

DOI:10.1080/10402000008982411

upstream raw materials:

di(p-nitrophenyl) disulfide

bis(4-nitrophenyl)sulfide

diphenyl sulfide

nitric acid

Downstream raw materials:

4-nitrophenyl sulfone

di(p-nitrophenyl) disulfide

p-nitrobenzenesulphinamide

4-<18F>-fluoronitrobenzene

Refernces

• 1、 Abel, A. S.,Averin, A. D.,Beletskaya, I. P.,Bessmertnykh-Lemeune, A. G.,Yakushev, A. A.,Zenkov, I. S.. "Photocatalytic Activity of Ruthenium(II) Complex with 1,10-Phenanthroline-3,8-dicarboxylic Acid in Aerobic Oxidation Reactions". . p. 1398 - 1404. Retrieved 2021/10/26.
• 2、 -. "Process for the selective hydrogenation of carbon two fractions (by machine translation)". Paragraph 0036 - 0038. . Retrieved 2017/03/28.