(CyP(CH₂CSiMe₂NSiMe₂CH₂)2PCy)NbCl

Base Information

Chemical Name:(CyP(CH₂CSiMe₂NSiMe₂CH₂)2PCy)NbCl
CAS No.:362591-29-5
Molecular Formula:C₂₄H₅₄ClN₂NbP₂Si₄
Molecular Weight:673.355
Hs Code.:

(CyP(CH<sub>2</sub>CSiMe<sub>2</sub>NSiMe<sub>2</sub>CH<sub>2</sub>)2PCy)NbCl

Synonyms:(CyP(CH₂CSiMe₂NSiMe₂CH₂)2PCy)NbCl

Suppliers and Price of (CyP(CH₂CSiMe₂NSiMe₂CH₂)2PCy)NbCl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (CyP(CH₂CSiMe₂NSiMe₂CH₂)2PCy)NbCl

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (CyP(CH₂CSiMe₂NSiMe₂CH₂)2PCy)NbCl

There total 1 articles about (CyP(CH₂CSiMe₂NSiMe₂CH₂)2PCy)NbCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 110615-13-9
niobium(III) chloride dimethoxyethane

: (C₆H₁₁P(CH₂Si(CH₃)2NSi(CH₃)2CH₂)2PC₆H₁₁)Li₂(OC₄H₈)

: 362591-29-5
(CyP(CH₂CSiMe₂NSiMe₂CH₂)2PCy)NbCl

Guidance literature:: In toluene; mixt. Cy(P2N2)Li2(THF) and NbCl3(DME) was suspended in toluene and stirred for 2 days; soln. evapd. to dryness, extd. into toluene and filtered, toluene was removed in vacuo, residue was washed with hexane and crystd. from toluene;elem. anal.;
DOI:10.1021/om010356z

Reference yield: 85.0%

: 362591-29-5
NbCl(PC₆H₁₁)2(CH₂Si(CH₃)2)4N₂

: 676-58-4
methylmagnesium chloride

: 583878-58-4
NbCH₃(PC₆H₁₁)2(CH₂Si(CH₃)2)4N₂

Guidance literature:: In toluene; byproducts: MgCl2; MeMgCl was added to a stirred soln. of complex in toluene under Ar, stirred for 6 h; solvent was removed under vac., the residue was extd. with toluene, filtered, toluene was removed, the solid was washed with hexane; elem. anal.;
DOI:10.1016/S0020-1693(02)01305-1

Reference yield: 78.0%

: 362591-29-5
(CyP(CH₂CSiMe₂NSiMe₂CH₂)2PCy)NbCl

: 1333-74-0
hydrogen

: 108-88-3,15644-74-3,16713-13-6
toluene

: 477332-51-7
(cyclohexyl)P(CH2SiMe2NSiMe2CH2)2P(cyclohexyl)Nb(η5-C7H9)

Guidance literature:: With KC₈; In toluene; under N2 or Ar; Nb-contg. compd. (0.758 mmol) and KC8 (0.830 mmol) were loaded into a thick walled glass reactor; H2 was added to the frozen soln. at -196°C; the sealed reactor was allowed to warm to room temp.; stirring for 24 h; the mixt. was filtered and the solvents removed in vac.; the solid was extd. with min. hexanes and slow cooled to -40°C; elem. anal.;
DOI:10.1021/om020395q