bis(nitrosobenzene){2,37,8,12,13,17,18-octaethylporphyrinato^(2-)}ruthenium⁽²⁺⁾

Base Information

• Chemical Name: bis(nitrosobenzene){2,37,8,12,13,17,18-octaethylporphyrinato^(2-)}ruthenium⁽²⁺⁾
• CAS No.: 113469-04-8
• Molecular Formula: C₄₈H₅₄N₆O₂Ru
• Molecular Weight: 848.066
• Mol file: 113469-04-8.mol

Synonyms:bis(nitrosobenzene){2,37,8,12,13,17,18-octaethylporphyrinato^(2-)}ruthenium⁽²⁺⁾

Chemical Property of bis(nitrosobenzene){2,37,8,12,13,17,18-octaethylporphyrinato^(2-)}ruthenium⁽²⁺⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(nitrosobenzene){2,37,8,12,13,17,18-octaethylporphyrinato^(2-)}ruthenium⁽²⁺⁾

There total 1 articles about bis(nitrosobenzene){2,37,8,12,13,17,18-octaethylporphyrinato^(2-)}ruthenium⁽²⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

carbonyl-ethanol{2,3,7,8,12,13,17,18-octaethylporphyrinato(2-)}ruthenium(2+) (55059-73-9) + Nitrosobenzene (586-96-9) → bis(nitrosobenzene){2,37,8,12,13,17,18-octaethylporphyrinato(2-)}ruthenium(2+) (113469-04-8)

Guidance literature:

In dichloromethane; treatment of 0.2 mmol Ru complex with 0.5 mmol PhNO in CH2Cl2 at ca. 20°C under N2; removal of solvent by evapn.; solid recrystd. from boiling hexane; elem. anal.;

DOI:10.1016/S0020-1693(00)86366-5

Reference yield: 100.0%

pyridine (110-86-1) + bis(nitrosobenzene){2,37,8,12,13,17,18-octaethylporphyrinato(2-)}ruthenium(2+) (113469-04-8) → Ru{C20H4N4(C2H5)8}(C6H5NO)(C5H5N) (113469-06-0)

Guidance literature:

In dichloromethane; treatment of the Ru complex with 2 mol equiv. of pyridine at 20°C for 10 min; elem. anal.;

DOI:10.1016/S0020-1693(00)86366-5

Reference yield:

bis(nitrosobenzene){2,37,8,12,13,17,18-octaethylporphyrinato(2-)}ruthenium(2+) (113469-04-8) → 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine ruthenium(II) carbonyl (41636-35-5) + Nitrosobenzene (586-96-9)

Guidance literature:

With carbon monoxide; In dichloromethane; CH2Cl2 soln. of the Ru complex subjected to 1 atm CO; Ru(OEP)(PhNO)(CO) detected in situ at lower temps. (<-40°C);

DOI:10.1016/S0020-1693(00)86366-5

upstream raw materials:

carbonyl-ethanol{2,3,7,8,12,13,17,18-octaethylporphyrinato^(2-)}ruthenium⁽²⁺⁾

Nitrosobenzene

Downstream raw materials:

Ru{C₂₀H₄N₄(C₂H₅)8}(C₆H₅NO)(C₅H₅N)

2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine ruthenium(II) carbonyl

Nitrosobenzene

nitrosobenzene{2,3,7,8,12,13,17,18-octaethylporhyrinato^(2-)}ruthenium⁽²⁺⁾