diethyl ether ; compound with aluminium trichloride

Base Information

• Chemical Name: diethyl ether ; compound with aluminium trichloride
• CAS No.: 17634-40-1
• Molecular Formula: AlCl₃*C₄H₁₀O
• Molecular Weight: 207.463
• Mol file: 17634-40-1.mol

Synonyms:diethyl ether ; compound with aluminium trichloride

Chemical Property of diethyl ether ; compound with aluminium trichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diethyl ether ; compound with aluminium trichloride

There total 4 articles about diethyl ether ; compound with aluminium trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 7.0%

aluminum(I) chloride + diethyl ether (60-29-7,927820-24-4) + toluene (108-88-3,15644-74-3,16713-13-6) + lithium hexamethyldisilazane (4039-32-1) → 54Al*15Al(1+)*18N(SiC3H9)2(1-)*2Li(OC4H10)3(1+)*Li(OC4H10)4(1+)*1.5C6H5CH3=[Al69N18Si36C108H324](C40H100Li3O10)*1.5C7H8 + diethyl ether ; compound with aluminium trichloride (17634-40-1) + aluminium (7429-90-5)

Guidance literature:

In diethyl ether; toluene; byproducts: LiCl*3Et2O; soln. of AlCl in toluene/Et2O (3/1) was added to LiN(SiMe3)2 at -78°C; soln. was warmed to room temp. within 1 d; heated at 60°C for 1 h; filtered; soln. was left at 60°C for 2 mo; pptd.;

DOI:10.1021/ic0104297

Reference yield: 5.0%

aluminum(I) chloride + diethyl ether (60-29-7,927820-24-4) + toluene (108-88-3,15644-74-3,16713-13-6) + lithium hexamethyldisilazane (4039-32-1) → 54Al*15Al(1+)*18N(Si(CH3)3)2(1-)*3Li(O(C2H5)2)4(1+)*6C6H5CH3=[Al69(N(Si(CH3)3)2)18](Li(O(C2H5)2)4)3*6C6H5CH3 + diethyl ether ; compound with aluminium trichloride (17634-40-1) + aluminium (7429-90-5)

Guidance literature:

In diethyl ether; toluene; byproducts: LiCl*3Et2O; gaseous AlCl were condensed with toluene and diethyl ether at -196°C; soln. of AlCl*Et2O was added to LiN(SiMe3)2 at 25°C; mixt. was left for 1 h; filtered; soln. was heated at 60°C for 1.5 h; pptd.;

DOI:10.1021/ic0104297

Reference yield:

aluminum chloride*99Et2O → diethyl ether ; compound with aluminium trichloride (17634-40-1) + aluminium (7429-90-5)

Guidance literature:

In toluene; Decompn. of starting soln. occurs at room temp. within a few hours.; Pptn. of metallic Al. IR spectroscopy.;

upstream raw materials:

hydrogenchloride

diethyl ether

toluene

lithium hexamethyldisilazane

Downstream raw materials:

ethene

chloroethane

Refernces

• 1、 Koehnlein,Purath,Klemp,Baum,Krossing,Stoesser,Schnoeckel. "Synthesis and characterization of an Al693- cluster with 51 naked Al atoms: Analogies and differences to the previously characterized Al772- cluster". . p. 4830 - 4838. Retrieved 2001.