trimethyl(4-tetrahydro-2H-2-pyranyloxyphenyl)stannane

Base Information

• Chemical Name: trimethyl(4-tetrahydro-2H-2-pyranyloxyphenyl)stannane
• CAS No.: 108613-04-3
• Molecular Formula: C₁₄H₂₂O₂Sn
• Molecular Weight: 341.037
• Mol file: 108613-04-3.mol

Synonyms:trimethyl(4-tetrahydro-2H-2-pyranyloxyphenyl)stannane

Chemical Property of trimethyl(4-tetrahydro-2H-2-pyranyloxyphenyl)stannane

Chemical Property:

Purity/Quality:

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Technology Process of trimethyl(4-tetrahydro-2H-2-pyranyloxyphenyl)stannane

There total 2 articles about trimethyl(4-tetrahydro-2H-2-pyranyloxyphenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

4-chlorophenyl tetrahydro-2H-pyran-2-yl ether (20443-90-7) + trimethyltin(IV)chloride (1066-45-1) + sodium (7440-23-5) → trimethyl(4-tetrahydro-2H-2-pyranyloxyphenyl)stannane (108613-04-3)

Guidance literature:

In ammonia; Irradiation (UV/VIS);

DOI:10.1016/j.jorganchem.2005.05.023

Reference yield: 82.0%

O,O-diethyl O-4-tetrahydro-2H-2-pyranyloxyphenyl phosphate (866927-59-5) + trimethyltin(IV)chloride (1066-45-1) + sodium (7440-23-5) → trimethyl(4-tetrahydro-2H-2-pyranyloxyphenyl)stannane (108613-04-3)

Guidance literature:

In ammonia; Irradiation (UV/VIS); under inert atm.; into flask cooled with acetone-liq. N2 was condensed NH3; Me3SnCl dissolved; Na added; O,O-diethyl O-4-tetrahydro-2H-2-pyranyloxyphenyl phosphate added; soln. irradiated with stirring for 4 h; quenched by adding NH4Cl in excess; NH3 allowed to evap.; residue treated (H2O); extd. (Et2O); extracts washed (brine); dried (MgSO4); solvent removed; as oil;

DOI:10.1016/j.jorganchem.2005.05.023

Reference yield: 50.0%

N,N-dimethyl(methylene)ammonium chloride (30354-18-8) + trimethyl(4-tetrahydro-2H-2-pyranyloxyphenyl)stannane (108613-04-3) → 4-((dimethylamino)methyl)phenol (103-87-7) + Dimethyl-[4-(tetrahydro-pyran-2-yloxy)-benzyl]-amine

Guidance literature:

In dichloromethane; for 15h; Heating;

DOI:10.1016/S0040-4039(00)85120-5

upstream raw materials:

4-chlorophenyl tetrahydro-2H-pyran-2-yl ether

trimethyltin(IV)chloride

sodium

O,O-diethyl O-4-tetrahydro-2H-2-pyranyloxyphenyl phosphate

Downstream raw materials:

4-((dimethylamino)methyl)phenol

4'-methoxy-1,1'-biphenyl-4-ol

2-phenoxytetrahydropyran

phenyl(4-((tetrahydro-2H-pyran-2-yl)oxy)phenyl)methanone