[Ru(η5-indenyl)H(triphenylphosphine)(dicyclohexylphosphine)]

Base Information

• Chemical Name: [Ru(η5-indenyl)H(triphenylphosphine)(dicyclohexylphosphine)]
• CAS No.: 870854-26-5
• Molecular Formula: C₃₉H₄₆P₂Ru
• Molecular Weight: 677.812
• Mol file: 870854-26-5.mol

Synonyms:[Ru(η5-indenyl)H(triphenylphosphine)(dicyclohexylphosphine)]

Chemical Property of [Ru(η5-indenyl)H(triphenylphosphine)(dicyclohexylphosphine)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of [Ru(η5-indenyl)H(triphenylphosphine)(dicyclohexylphosphine)]

There total 4 articles about [Ru(η5-indenyl)H(triphenylphosphine)(dicyclohexylphosphine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

methanol (67-56-1) + RuCl(η5-indenyl)(PHCy2)(PPh3) (870854-21-0) → [Ru(η5-indenyl)H(triphenylphosphine)(dicyclohexylphosphine)] (870854-26-5)

Guidance literature:

With NaOCH₃; In methanol; byproducts: NaCl, H2CO; (N2); a soln. of NaOCH3 added to a suspn. of Ru complex, stirred at roomtemp. for 2 d; filtered, washed (dry MeOH, hexanes), dried (vac.); elem. anal.;

DOI:10.1021/om050259w

Reference yield:

[Ru(η5-indenyl)(OMe)(HP(C6H11)2)(PPh3)] (1067236-27-4) → [Ru(η5-indenyl)H(triphenylphosphine)(dicyclohexylphosphine)] (870854-26-5)

Guidance literature:

In ⁽²⁾H₈-toluene; under N2; soln. of Ru complex in toluene-d8 warmed from 240 K to room temp.; not isolated; monitored by (31)P NMR spectra;

DOI:10.1021/om800343x

Reference yield:

[Ru(η5-indenyl)(PCy2)(PPh3)]*0.25(pentane) + hydrogen (1333-74-0) → [Ru(η5-indenyl)H(triphenylphosphine)(dicyclohexylphosphine)] (870854-26-5)

Guidance literature:

In benzene-d6; (vac.); exposure of soln. of ruthenium compd. to hydrogen atmosphere; (1)H NMR monitoring;

DOI:10.1021/om0700056

upstream raw materials:

methanol

RuCl(η⁵-indenyl)(PHCy₂)(PPh₃)

hydrogen

[ruthenium(η5-indenyl)(PPh3)(P(Cy)2)]