[5-(7-bromo-1-p-tolylsulfanyl-heptyl)-2-methoxy-phenoxy]-tert-butyl-dimethyl-silane

Base Information

Chemical Name:[5-(7-bromo-1-p-tolylsulfanyl-heptyl)-2-methoxy-phenoxy]-tert-butyl-dimethyl-silane
CAS No.:167159-48-0
Molecular Formula:C₂₇H₄₁BrO₂SSi
Molecular Weight:537.677
Hs Code.:

[5-(7-bromo-1-<i>p</i>-tolylsulfanyl-heptyl)-2-methoxy-phenoxy]-<i>tert</i>-butyl-dimethyl-silane

Synonyms:[5-(7-bromo-1-p-tolylsulfanyl-heptyl)-2-methoxy-phenoxy]-tert-butyl-dimethyl-silane

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Chemical Property of [5-(7-bromo-1-p-tolylsulfanyl-heptyl)-2-methoxy-phenoxy]-tert-butyl-dimethyl-silane

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Technology Process of [5-(7-bromo-1-p-tolylsulfanyl-heptyl)-2-methoxy-phenoxy]-tert-butyl-dimethyl-silane

There total 4 articles about [5-(7-bromo-1-p-tolylsulfanyl-heptyl)-2-methoxy-phenoxy]-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4383-06-6
3-hydroxy-4-methoxybenzyl alcohol

: 167159-48-0
[5-(7-bromo-1-p-tolylsulfanyl-heptyl)-2-methoxy-phenoxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: HBr(g) / toluene / 0.5 h / 0 °C

2: aq. KOH, (Bu)4NHSO₄ / toluene / 12 h / 25 °C

3: 94 percent / 4-(dimethylamino)pyridine / pyridine / Heating

4: 1.) N-BuLi, phenanthroline / 1.) THF, hexane, from -78 deg C to O deg C, 2.) THF, hexane, from -78 deg C to 25 deg C

With dmap; potassium hydroxide; n-butyllithium; Phenanthroline; hydrogen bromide; tetra(n-butyl)ammonium hydrogensulfate; In pyridine; toluene;
DOI:10.1021/jm9804477

Reference yield:

: 111394-51-5
3-hydroxy-4-methoxybenzyl bromide

: 167159-48-0
[5-(7-bromo-1-p-tolylsulfanyl-heptyl)-2-methoxy-phenoxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: aq. KOH, (Bu)4NHSO₄ / toluene / 12 h / 25 °C

2: 94 percent / 4-(dimethylamino)pyridine / pyridine / Heating

3: 1.) N-BuLi, phenanthroline / 1.) THF, hexane, from -78 deg C to O deg C, 2.) THF, hexane, from -78 deg C to 25 deg C

With dmap; potassium hydroxide; n-butyllithium; Phenanthroline; tetra(n-butyl)ammonium hydrogensulfate; In pyridine; toluene;
DOI:10.1021/jm9804477

Reference yield:

: 167159-68-4
2-methoxy-5-<<(4-methylphenyl)thio>methyl>phenol

: 167159-48-0
[5-(7-bromo-1-p-tolylsulfanyl-heptyl)-2-methoxy-phenoxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / 4-(dimethylamino)pyridine / pyridine / Heating

2: 1.) N-BuLi, phenanthroline / 1.) THF, hexane, from -78 deg C to O deg C, 2.) THF, hexane, from -78 deg C to 25 deg C

With dmap; n-butyllithium; Phenanthroline; In pyridine;
DOI:10.1021/jm9804477