nickel dicarbonyl

Base Information

• Chemical Name: nickel dicarbonyl
• CAS No.: 33637-77-3
• Molecular Formula: C₂NiO₂
• Molecular Weight: 114.711
• Mol file: 33637-77-3.mol

Synonyms:nickel dicarbonyl

Chemical Property of nickel dicarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of nickel dicarbonyl

There total 2 articles about nickel dicarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetracarbonyl nickel (13463-39-3,71564-36-8) → nickel monocarbonyl (33637-76-2,65991-72-2) + nickel dicarbonyl (33637-77-3) + nickel tricarbonyl (26024-55-5)

Guidance literature:

In gaseous matrix; byproducts: CO; Irradiation (UV/VIS); photofragmentation (ArF-, KrF- andXeCl-excimer laser, 193, 248 and 308 nm) of Ni(CO)4 in He carrier gas from supersonic jet;

DOI:10.1063/1.459434

Reference yield:

carbon monoxide (201230-82-2) + nickel dichloride (83864-14-6) → nickel monocarbonyl (33637-76-2,65991-72-2) + nickel dicarbonyl (33637-77-3) + nickel dichloride (173074-30-1,83864-14-6) + (58)Ni(CO)2(35)Cl2 + chloroformyl radical (2602-42-8)

Guidance literature:

In solid matrix; the laser-ablated NiCl2 (1064 nm) was codeposed with CO in excess argon onto a 11 K CsI window for 1 h at a rate of 2-4 mmol/h; further products; not sepd., detected by IR spectra,;

DOI:10.1021/om000911h

Reference yield:

nickel dicarbonyl (33637-77-3) + Bis(o-carboxyphenylaminomethyl)phenylphosphine (124910-24-3) → di-P,P'-(bis(o-carboxyphenylaminomethyl)phenylphosphine)dicarbonylnickel(0) (162974-05-2)

Guidance literature:

upstream raw materials:

tetracarbonyl nickel

carbon monoxide

nickel dichloride

Downstream raw materials:

di-P,P'-(bis(o-carboxyphenylaminomethyl)phenylphosphine)dicarbonylnickel⁽⁰⁾