3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-D-glucopyranose

Base Information

• Chemical Name: 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-D-glucopyranose
• CAS No.: 84635-46-1
• Molecular Formula: C₁₈H₂₁N₃O₁₂
• Molecular Weight: 471.378
• Mol file: 84635-46-1.mol

Synonyms:3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-D-glucopyranose

Chemical Property of 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-D-glucopyranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-D-glucopyranose

There total 10 articles about 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1-methoxy-1-methylethyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranoside (84635-45-0) → 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranose (84635-46-1)

Guidance literature:

With acetic acid; at 90 ℃; for 0.666667h;

DOI:10.1246/bcsj.55.3665

Reference yield: 87.0%

1,3,4,6-tetra-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-α-D-glucopyranose (7784-55-6) → 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-D-glucopyranose (84635-46-1)

Guidance literature:

With hydrazinium monoacetate; In N,N-dimethyl-formamide; at 20 ℃; for 2h;

DOI:10.1016/j.tetlet.2017.06.037

Reference yield: 57.0%

methanol (67-56-1) + acetone (67-64-1) + 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranosyl bromide (3068-36-8) → 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranose (84635-46-1) + 1-methoxy-1-methylethyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranoside (84635-45-0)

Guidance literature:

With tetrabutylammomium bromide; mercury(II) cyanide; mercury dibromide; for 24h; Ambient temperature;

DOI:10.1246/bcsj.55.3665

upstream raw materials:

1-methoxy-1-methylethyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranoside

1,3,4,6-tetra-O-benzyl-α,β-D-fructofuranose

3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranosyl bromide

methanol

Downstream raw materials:

benzyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-β-D-glucopyranoside

benzyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitrophenylamino)-α-D-glucopyranoside