[Pt(IV)BrMe₂(CH₂-4-C₆H₄CO₂H)(4,4'-di-tert-butyl-2,2'-bipyridine)]

Base Information

• Chemical Name: [Pt(IV)BrMe₂(CH₂-4-C₆H₄CO₂H)(4,4'-di-tert-butyl-2,2'-bipyridine)]
• CAS No.: 266687-78-9
• Molecular Formula: C₂₈H₃₇BrN₂O₂Pt
• Molecular Weight: 708.598
• Mol file: 266687-78-9.mol

Synonyms:[Pt(IV)BrMe₂(CH₂-4-C₆H₄CO₂H)(4,4'-di-tert-butyl-2,2'-bipyridine)]

Chemical Property of [Pt(IV)BrMe₂(CH₂-4-C₆H₄CO₂H)(4,4'-di-tert-butyl-2,2'-bipyridine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of [Pt(IV)BrMe₂(CH₂-4-C₆H₄CO₂H)(4,4'-di-tert-butyl-2,2'-bipyridine)]

There total 1 articles about [Pt(IV)BrMe₂(CH₂-4-C₆H₄CO₂H)(4,4'-di-tert-butyl-2,2'-bipyridine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

(4,4'-di-tert-butyl-2,2'-bipyridine)dimethylplatinum(II) + 4-bromomethylbenzoic Acid (6232-88-8) → [Pt(IV)BrMe2(CH2-4-C6H4CO2H)(4,4'-di-tert-butyl-2,2'-bipyridine)] (266687-78-9)

Guidance literature:

In acetone; under N2; stirring mixt. of Pt complex and BrCH2C6H4CO2H in acetone for5 h at room temp.; evapn. under vac., recrystn. from acetone/pentane; elem. anal.;

DOI:10.1021/om990942g

Reference yield: 88.0%

silver tetrafluoroborate (14104-20-2) + [Pt(IV)BrMe2(CH2-4-C6H4CO2H)(4,4'-di-tert-butyl-2,2'-bipyridine)] (266687-78-9) + acetone (67-64-1) → [Pt(IV)Me2(CH2-4-C6H4CO2H)(4,4'-di-tert-butyl-2,2'-bipyridine)(H2O)]BF4*Me2CO

Guidance literature:

In acetone; byproducts: AgBr; under N2, Schlenk technique; soln. of AgBF4 in acetone was added dropwise to soln. of complex in acetone, mixt. was stirred for 1 h, AgBr was filtered off, stirring for 2 h at room temp.; solvent was evapd., ppt. was washed with pentane; elem. anal.;

DOI:10.1139/V09-031

Reference yield: 86.0%

4,4'-bipyridine (553-26-4) + silver tetrafluoroborate (14104-20-2) + [Pt(IV)BrMe2(CH2-4-C6H4CO2H)(4,4'-di-tert-butyl-2,2'-bipyridine)] (266687-78-9) + water (7732-18-5) → [(Pt(CH3)2((NC5H3C(CH3)3)2)(CH2C6H4CO2H))2((NC5H4)2)](2+)*2[BF4](1-)*H2O

Guidance literature:

In acetone; byproducts: AgBr; under N2; dropwise addn. of soln. of AgBF4 in acetone to soln. of Pt complex in acetone, react. time = 30 min, filtration through Celite into soln. of 4,4'-bipyridyl in acetone, react. time = 5 h; evapn., recrystn. from CH2Cl2/pentane; elem. anal.;

DOI:10.1021/om990942g

upstream raw materials:

4-bromomethylbenzoic Acid