(E)-[5,5-dimethyl-6-(3-oxobut-1-enyl)cyclohex-1-enyl]methyl acetate

Base Information

• Chemical Name: (E)-[5,5-dimethyl-6-(3-oxobut-1-enyl)cyclohex-1-enyl]methyl acetate
• CAS No.: 80704-08-1
• Molecular Formula: C₁₅H₂₂O₃
• Molecular Weight: 250.338
• Mol file: 80704-08-1.mol

Synonyms:(E)-[5,5-dimethyl-6-(3-oxobut-1-enyl)cyclohex-1-enyl]methyl acetate

Chemical Property of (E)-[5,5-dimethyl-6-(3-oxobut-1-enyl)cyclohex-1-enyl]methyl acetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-[5,5-dimethyl-6-(3-oxobut-1-enyl)cyclohex-1-enyl]methyl acetate

There total 1 articles about (E)-[5,5-dimethyl-6-(3-oxobut-1-enyl)cyclohex-1-enyl]methyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.0%

alpha-ionone (127-41-3,6901-97-9,14398-36-8,24190-29-2,30685-95-1,31798-12-6,52340-45-1,67529-94-6,67529-95-7) + silver(I) acetate (563-63-3) → (E)-[5,5-dimethyl-6-(3-oxobut-1-enyl)cyclohex-1-enyl]methyl acetate (80704-08-1)

Guidance literature:

With iodine; In benzene; at 100 ℃; for 2.5h;

DOI:10.1016/j.bmcl.2007.06.018

Reference yield: 20.0%

(E)-[5,5-dimethyl-6-(3-oxobut-1-enyl)cyclohex-1-enyl]methyl acetate (80704-08-1) → (E)-[5,5-dimethyl-3-oxo-6-(3-oxobut-1-enyl)cyclohex-1-enyl]methyl acetate (951171-22-5)

Guidance literature:

With tert.-butylhydroperoxide; dipyridinium dichromate; In dichloromethane; at 20 ℃; for 18.5h;

DOI:10.1016/j.bmcl.2007.06.018

Reference yield: 10.0%

(E)-[5,5-dimethyl-6-(3-oxobut-1-enyl)cyclohex-1-enyl]methyl acetate (80704-08-1) → (E)-[6-hydroxy-5,5-dimethyl-3-oxo-6-(oxobut-1-enyl)cyclohex-1-enyl]methyl acetate (951171-17-8)

Guidance literature:

With acetic anhydride; t-butyl chromate; In tert-butyl alcohol; for 2h; Heating;

DOI:10.1016/j.bmcl.2007.06.018

upstream raw materials:

alpha-ionone

silver(I) acetate

Downstream raw materials:

(E)-[5,5-dimethyl-3-oxo-6-(3-oxobut-1-enyl)cyclohex-1-enyl]methyl acetate

(E)-[6-hydroxy-5,5-dimethyl-3-oxo-6-(oxobut-1-enyl)cyclohex-1-enyl]methyl acetate

C₁₈H₂₄O₅

(+/-)-1'-deoxy-7'-hydroxyabscisic acid